| Titre : | Effect of total dopant concentration and dopant ratio on conductivity of (DyO1.5)x–(WO3)y–(BiO1.5)1−x−y |
| Auteurs : | Doh Won Jung, Auteur ; Keith L. Duncan, Auteur ; Eric D. Wachsman, Auteur |
| Type de document : | Article : texte imprimé |
| Dans : | Acta materialia (Vol. 58 N° 2, Janvier 2010) |
| Article en page(s) : | pp. 355-363 |
| Note générale : | Métallurgie |
| Langues : | Anglais |
| Index. décimale : | 669 (Métallurgie) |
| Tags : | Solid electrolytes Bismuth oxide Lattice parameter Conductivity Total dopant concentration |
| Résumé : |
Dysprosium- and tungsten-stabilized bismuth oxide (DWSB) electrolytes were developed to achieve higher conductivity.
With double doping, stabilization of the cubic phase was achieved with as little as 12 mol.% total dopant concentration, resulting in higher conductivity. The conductivity of DWSB electrolytes increased linearly as the total dopant concentrations decreased with fixed dopant ratio. Overall, DWSB has a closer inherent structure to pure δ-Bi2O3 than any singly doped compositions. Both lattice parameter and conductivity linearly extrapolate with total dopant concentration to that of pure δ-Bi2O3, resulting in the ability to stabilize δ-phase at lower dopant concentration, and thus achieving higher conductivity. |
| DEWEY : | 669 |
| ISSN : | 1359-6454 |
| En ligne : | http://www.sciencedirect.com/science?_ob=PublicationURL&_tockey=%23TOC%235556%232010%23999419997%231562200%23FLA%23&_cdi=5556&_pubType=J&_auth=y&_acct=C000070790&_version=1&_urlVersion=0&_userid=6909337&md5=b76b02a9bf437ba6ba8077be7b9830f5 |
