| Titre : | Direct oxidation of methane to a methanol derivative using molecular oxygen (2011) |
| Auteurs : | Jiongliang Yuan, Auteur ; Lanlan Wang, Auteur ; Yan Wang, Auteur |
| Type de document : | Article : texte imprimé |
| Dans : | Industrial & engineering chemistry research (Vol. 50 N° 10, Mai 2011) |
| Article en page(s) : | pp. 6513-6516 |
| Note générale : | Chimie industrielle |
| Langues : | Anglais |
| Tags : | Oxidation |
| Résumé : | A direct selective oxidation of methane to a methanol derivative with the catalysis of palladium acetate/ benzoquinone/molybdovanado-phosphoric acid using molecular oxygen in trifluoroacetic acid has been suggested. Methyl trifluoroacetate is the only liquid product, and its highest yield could be obtained at 80-100 °C. The addition of perfluorooctane could improve the yield of methyl trifluoroacetate significantly. The reaction product can be easily separated from the reaction system, using the difference of boiling points. |
| DEWEY : | 660 |
| ISSN : | 0888-5885 |
| En ligne : | http://cat.inist.fr/?aModele=afficheN&cpsidt=24158950 |
