| Titre : | Cysteine - based organocatalysts for the highly efficient direct stoichiometric anti - and syn - aldol reactions (2012) |
| Auteurs : | Shi Li, Auteur ; Chuanlong Wu, Auteur ; Xiangkai Fu, Auteur |
| Type de document : | Article : texte imprimé |
| Dans : | Industrial & engineering chemistry research (Vol. 50 N° 24, Décembre 2011) |
| Article en page(s) : | pp. 13711-13716 |
| Note générale : | Chimie industrielle |
| Langues : | Anglais |
| Tags : | Organocatalysts Stoichiometric |
| Résumé : | A series of cysteine-based organocatalysts have been designed and synthesized from a simple step. The anti-aldol and syn-aldol products could be obtained with up to 98:2 anti/syn and 99% ee; the stoichiometric ratio between aldehydes and ketones is 1. This catalyst could be easily recovered and efficiently used in large-scale reactions, which demonstrates its potential application in industry. |
| DEWEY : | 660 |
| ISSN : | 0888-5885 |
| En ligne : | http://pubs.acs.org/doi/abs/10.1021/ie201482c |
