| Titre : | Asymmetric hydrogenation of nonfunctionalized olefins in propylene carbonate — kinetic or thermodynami control? (2012) |
| Auteurs : | Sergey P. Verevkin, Auteur ; Vladimir N. Emel'yanenko, Auteur |
| Type de document : | Article : texte imprimé |
| Dans : | Industrial & engineering chemistry research (Vol. 51 N° 1, Janvier 2012) |
| Article en page(s) : | pp. 126-132 |
| Note générale : | Chimie industrielle |
| Langues : | Anglais |
| Tags : | Kinetics Hydrogenation |
| Résumé : | Iridium-catalyzed hydrogenations of nonfunctionalized olefins in propylene carbonate as the solvent allow efficient catalysis with much higher enantioselectivities in comparison with dichloromethane which is usually employed for these reactions. Experimental and computational studies of the hydrogenation of 1-methylene-1,2,3,4-tetrahydronaphthalene have been performed to understand the limitation for this reaction. |
| DEWEY : | 660 |
| ISSN : | 0888-5885 |
| En ligne : | http://cat.inist.fr/?aModele=afficheN&cpsidt=25476454 |
