| Titre : | Application of simplified PC - SAFT to glycol ethers (2012) |
| Auteurs : | Ane S. Avlund, Auteur ; Georgios M. Kontogeorgis, Auteur ; Michael L. Michelsen, Auteur |
| Type de document : | Article : texte imprimé |
| Dans : | Industrial & engineering chemistry research (Vol. 51 N° 1, Janvier 2012) |
| Article en page(s) : | pp. 547–555 |
| Note générale : | Chimie industrielle |
| Langues : | Anglais |
| Tags : | Glycol ethers Methoxyethanol Ethoxyethanol |
| Résumé : | The simplified PC-SAFT (sPC-SAFT) equation of state is applied for binary glycol ether-containing mixtures, and it is investigated how the results are influenced by inclusion of intramolecular association in the association theory. Three different glycol ethers are examined: 2-methoxyethanol, 2-ethoxyethanol, and 2-butoxyethanol. Vapor–liquid and liquid–liquid equilibria of miscible and immiscible, self- and cross-associating mixtures are considered, including the closed-loop liquid–liquid equilibrium of 2-butoxyethanol–water. The results are finally compared to other association models. |
| DEWEY : | 660 |
| ISSN : | 0888-5885 |
| En ligne : | http://pubs.acs.org/doi/abs/10.1021/ie2011406 |
