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Détail de l'indexation
M002297
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Ouvrages de la bibliothèque en indexation M002297
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Etude cinétique de la dégradation thermique du PVC chargé au perchlorate d'ammonium / Melouani, Benyoucef
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Titre : Etude cinétique de la dégradation thermique du PVC chargé au perchlorate d'ammonium Type de document : texte imprimé Auteurs : Melouani, Benyoucef, Auteur ; Benbarkat, A., Directeur de thèse Editeur : [S.l.] : [s.n.] Année de publication : 1997 Importance : 144 f. Présentation : ill. Format : 30 cm. Note générale : Mémoire de Magister : Génie Chimique : Alger, Ecole Nationale Polytechnique : 1997
Bibliogr. f. 120 - 124 . Annexe f. 126 - 144Langues : Français (fre) Mots-clés : Polymère chargé ; Vieillissement ; Germination ; Thermodégradation ; Microscopie optique ; Paramètres cinétiques Index. décimale : M002297 Résumé : Les polymères chargés qui nous concernent sont utilisés comme combustibles solides, dans certains moteurs à combustion. Le travail est mené sur des échantillons de polychlorure de vinyle (PVC), chargé de perchlorate d'ammonium (NH4ClO4). La détermination des paramètres cinétiques est indispensable pour l'estimation de leur degré de vieillissement. Nous avons mis au point un dispositif expérimental, afin d'étudier l'influence de différents paramètres: la granulométrie et le taux de chargement de perchlorate d'ammonium, l'épaisseur du film de polymère, la vitesse de chauffage et la nature de l'atmosphère.
Deux méthodes d'analyse sont utilisées:
- L'analyse thermogravimétrique.
- La microscopie optique couplée à un traitement d'images.
Les résultats ont montré que les deux méthodes aboutissent aux mêmes conclusions.
Enfin, un modèle mathématique de la théorie de germination, basé sur les analyses de la microscopie optique, est proposé en vu de décrire le processus de dégradation du PVC chargé de NH4ClO4.Etude cinétique de la dégradation thermique du PVC chargé au perchlorate d'ammonium [texte imprimé] / Melouani, Benyoucef, Auteur ; Benbarkat, A., Directeur de thèse . - [S.l.] : [s.n.], 1997 . - 144 f. : ill. ; 30 cm.
Mémoire de Magister : Génie Chimique : Alger, Ecole Nationale Polytechnique : 1997
Bibliogr. f. 120 - 124 . Annexe f. 126 - 144
Langues : Français (fre)
Mots-clés : Polymère chargé ; Vieillissement ; Germination ; Thermodégradation ; Microscopie optique ; Paramètres cinétiques Index. décimale : M002297 Résumé : Les polymères chargés qui nous concernent sont utilisés comme combustibles solides, dans certains moteurs à combustion. Le travail est mené sur des échantillons de polychlorure de vinyle (PVC), chargé de perchlorate d'ammonium (NH4ClO4). La détermination des paramètres cinétiques est indispensable pour l'estimation de leur degré de vieillissement. Nous avons mis au point un dispositif expérimental, afin d'étudier l'influence de différents paramètres: la granulométrie et le taux de chargement de perchlorate d'ammonium, l'épaisseur du film de polymère, la vitesse de chauffage et la nature de l'atmosphère.
Deux méthodes d'analyse sont utilisées:
- L'analyse thermogravimétrique.
- La microscopie optique couplée à un traitement d'images.
Les résultats ont montré que les deux méthodes aboutissent aux mêmes conclusions.
Enfin, un modèle mathématique de la théorie de germination, basé sur les analyses de la microscopie optique, est proposé en vu de décrire le processus de dégradation du PVC chargé de NH4ClO4.Exemplaires
Code-barres Cote Support Localisation Section Disponibilité Spécialité Etat_Exemplaire M002297 M002297 Papier Bibliothèque centrale Mémoire de Magister Disponible Documents numériques
MELOUANI.Benyoucef.pdfURL