Utilization of Fennel biomass (Foeniculum vulgari) a medicinal herb for the biosorption of Cd(II) from aqueous phase / Rifaqat Ali Khan Rao in Chemical engineering journal, Vol. 156 N° 1 (Janvier 2010)  

Public ISBD [article]  inChemical engineering journal > Vol. 156 N° 1 (Janvier 2010) . - pp. 106-113 Titre : Utilization of Fennel biomass (Foeniculum vulgari) a medicinal herb for the biosorption of Cd(II) from aqueous phase Type de document : texte imprimé Auteurs : Rifaqat Ali Khan Rao, Auteur ; Moonis Ali Khan, Auteur ; Fouzia Rehman, Auteur Année de publication : 2010 Article en page(s) : pp. 106-113 Note générale : Génie Chimique Langues : Anglais (eng) Mots-clés : Fennel biomass Regeneration Biosorption Desorption Breakthrough capacity Index. décimale : 660 Résumé : This work presents the biosorption potential of Fennel biomass for the effective removal of Cd(II) ions. The biosorption was maximum (92%) at pH 4.3. Maximum biosorption capacities of Cd(II) at 30, 40 and 50 °C temperatures were 21, 24 and 30 mg/g, respectively. The biosorption of Cd(II) was concentration dependent and increases from 0.49 to 9.3 mg/g with increase in concentration from 5 to 100 mg/L. Biosorption follows Freundlich isotherm at 50 °C. Mean free energies at different temperatures were in between 7.1 and 11.95 kJ/mol indicating chemical nature of biosorption process. Kinetics studies showed that pseudo-second-order kinetics model was applicable to the data. The process was endothermic and spontaneous, the spontaneity of the process increases with increase in temperature. Regeneration studies showed a decrease in the recovery of Cd(II) from 99.8% to 41.7% in five consecutive cycles. 80% of the Cd(II) in single and multi-metal systems was recovered in 10 mL. Breakthrough and exhaustive capacities of Cd(II) in single metal system were 10 and 40 mg/g. For multi-metal systems in double distilled water the breakthrough and exhaustive capacities of Cd(II) were 2 and 12 mg/g. In saline solution the breakthrough and exhaustive capacities of Cd(II) were 0.8 and 4 mg/g. DEWEY : 660 ISSN : 1385-8947 En ligne : http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TFJ-4XF840K-2&_user=6 [...] [article] Utilization of Fennel biomass (Foeniculum vulgari) a medicinal herb for the biosorption of Cd(II) from aqueous phase [texte imprimé] / Rifaqat Ali Khan Rao, Auteur ; Moonis Ali Khan, Auteur ; Fouzia Rehman, Auteur . - 2010 . - pp. 106-113. Génie Chimique Langues : Anglais (eng) in Chemical engineering journal > Vol. 156 N° 1 (Janvier 2010) . - pp. 106-113 Mots-clés : Fennel biomass Regeneration Biosorption Desorption Breakthrough capacity Index. décimale : 660 Résumé : This work presents the biosorption potential of Fennel biomass for the effective removal of Cd(II) ions. The biosorption was maximum (92%) at pH 4.3. Maximum biosorption capacities of Cd(II) at 30, 40 and 50 °C temperatures were 21, 24 and 30 mg/g, respectively. The biosorption of Cd(II) was concentration dependent and increases from 0.49 to 9.3 mg/g with increase in concentration from 5 to 100 mg/L. Biosorption follows Freundlich isotherm at 50 °C. Mean free energies at different temperatures were in between 7.1 and 11.95 kJ/mol indicating chemical nature of biosorption process. Kinetics studies showed that pseudo-second-order kinetics model was applicable to the data. The process was endothermic and spontaneous, the spontaneity of the process increases with increase in temperature. Regeneration studies showed a decrease in the recovery of Cd(II) from 99.8% to 41.7% in five consecutive cycles. 80% of the Cd(II) in single and multi-metal systems was recovered in 10 mL. Breakthrough and exhaustive capacities of Cd(II) in single metal system were 10 and 40 mg/g. For multi-metal systems in double distilled water the breakthrough and exhaustive capacities of Cd(II) were 2 and 12 mg/g. In saline solution the breakthrough and exhaustive capacities of Cd(II) were 0.8 and 4 mg/g. DEWEY : 660 ISSN : 1385-8947 En ligne : http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TFJ-4XF840K-2&_user=6 [...]

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