Decomposition of perfluorinated ion-exchange membrane to fluoride ions using zerovalent metals in subcritical water / Hori, Hisao in Industrial & engineering chemistry research, Vol. 49 N° 2 (Janvier 2010)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 49 N° 2 (Janvier 2010) . - pp 464–471 Titre : Decomposition of perfluorinated ion-exchange membrane to fluoride ions using zerovalent metals in subcritical water Type de document : texte imprimé Auteurs : Hori, Hisao, Auteur ; Murayama, Misako, Auteur ; Sano, Taizo, Auteur Année de publication : 2010 Article en page(s) : pp 464–471 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Ion-exchange membrane Zerovalent metals. Résumé : The decomposition of Nafion NRE-212, a typical perfluorinated ion-exchange membrane used for fuel cells, in subcritical water was investigated. This is the first report of the decomposition of a perfluorinated ion-exchange membrane aimed at the development of a technique to recover the fluorine component for waste treatment. Although the membrane showed little decomposition in pure subcritical water, the addition of several zerovalent metals to the reaction system accelerated the membrane decomposition to F− ions, and the acceleration increased in the order Al DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie9004699 [article] Decomposition of perfluorinated ion-exchange membrane to fluoride ions using zerovalent metals in subcritical water [texte imprimé] / Hori, Hisao, Auteur ; Murayama, Misako, Auteur ; Sano, Taizo, Auteur . - 2010 . - pp 464–471. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 2 (Janvier 2010) . - pp 464–471 Mots-clés : Ion-exchange membrane Zerovalent metals. Résumé : The decomposition of Nafion NRE-212, a typical perfluorinated ion-exchange membrane used for fuel cells, in subcritical water was investigated. This is the first report of the decomposition of a perfluorinated ion-exchange membrane aimed at the development of a technique to recover the fluorine component for waste treatment. Although the membrane showed little decomposition in pure subcritical water, the addition of several zerovalent metals to the reaction system accelerated the membrane decomposition to F− ions, and the acceleration increased in the order Al DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie9004699

Exemplaires

Code-barres	Cote	Support	Localisation	Section	Disponibilité
aucun exemplaire