Melt differentiation and crystallization of clinker minerals in a CaO–SiO2–Al2O3–Fe2O3 pseudoquaternary system / Koichiro Fukuda in Cement and concrete research, Vol. 40 N° 1 (Janvier 2010)  

Public ISBD [article]  inCement and concrete research > Vol. 40 N° 1 (Janvier 2010) . - pp. 167-170 Titre : Melt differentiation and crystallization of clinker minerals in a CaO–SiO2–Al2O3–Fe2O3 pseudoquaternary system Type de document : texte imprimé Auteurs : Koichiro Fukuda, Auteur ; Tomoyuki Iwata, Auteur ; Hideto Yoshida, Auteur Article en page(s) : pp. 167-170 Note générale : Génie Civil Langues : Anglais (eng) Mots-clés : Microstructure Clinker Portland Cement Calcium aluminoferrite Melt differentiation Index. décimale : 691 Matériaux de construction. Pièces et parties composantes Résumé : In the CaO–SiO2–Al2O3–Fe2O3 pseudoquaternary system, the solid solutions of Ca3SiO5 [C3S(ss)], Ca2SiO4 [C2S(ss)], Ca2(AlxFe1 − x)2O5 with 0.40 ≤ x ≤ 0.57 (ferrite) and Ca3Al2O6 [C3A(ss)] were crystallized out of a complete melt with 52.9 mass% CaO and Al2O3/Fe2O3 = 0.70. When the melt was cooled from 1673 K at 80 K/h, the crystals of ferrite with x = 0.40, C3S(ss) and C2S(ss) would start to nucleate from the melt at 1630 K. During further cooling, the x value of the precipitating ferrite would progressively increase and eventually approach 0.57 at 1613 K. The resulting ferrite crystals showed a zonal structure, the x value of which successively increased from the cores toward the rims. Actually, the x values of 0.43 and 0.52 were confirmed for, respectively, the cores and rims by EPMA. As the simultaneous crystallization of zoned ferrite, C3S(ss) and C2S(ss) proceeded, the coexisting melt would become progressively enriched in the Al2O3 component. After the termination of the ferrite crystallization, the C3A(ss), C3S(ss) and C2S(ss) crystallized out of the differentiated melt. The end result was the four phase mixture of ferrite, C3A(ss), C3S(ss) and C2S(ss), being free from the nucleation of Ca12Al14O33 solid solution. DEWEY : 620.13 ISSN : 0008-8846 En ligne : http://www.sciencedirect.com/science?_ob=PublicationURL&_tockey=%23TOC%235562%23 [...] [article] Melt differentiation and crystallization of clinker minerals in a CaO–SiO2–Al2O3–Fe2O3 pseudoquaternary system [texte imprimé] / Koichiro Fukuda, Auteur ; Tomoyuki Iwata, Auteur ; Hideto Yoshida, Auteur . - pp. 167-170. Génie Civil Langues : Anglais (eng) in Cement and concrete research > Vol. 40 N° 1 (Janvier 2010) . - pp. 167-170 Mots-clés : Microstructure Clinker Portland Cement Calcium aluminoferrite Melt differentiation Index. décimale : 691 Matériaux de construction. Pièces et parties composantes Résumé : In the CaO–SiO2–Al2O3–Fe2O3 pseudoquaternary system, the solid solutions of Ca3SiO5 [C3S(ss)], Ca2SiO4 [C2S(ss)], Ca2(AlxFe1 − x)2O5 with 0.40 ≤ x ≤ 0.57 (ferrite) and Ca3Al2O6 [C3A(ss)] were crystallized out of a complete melt with 52.9 mass% CaO and Al2O3/Fe2O3 = 0.70. When the melt was cooled from 1673 K at 80 K/h, the crystals of ferrite with x = 0.40, C3S(ss) and C2S(ss) would start to nucleate from the melt at 1630 K. During further cooling, the x value of the precipitating ferrite would progressively increase and eventually approach 0.57 at 1613 K. The resulting ferrite crystals showed a zonal structure, the x value of which successively increased from the cores toward the rims. Actually, the x values of 0.43 and 0.52 were confirmed for, respectively, the cores and rims by EPMA. As the simultaneous crystallization of zoned ferrite, C3S(ss) and C2S(ss) proceeded, the coexisting melt would become progressively enriched in the Al2O3 component. After the termination of the ferrite crystallization, the C3A(ss), C3S(ss) and C2S(ss) crystallized out of the differentiated melt. The end result was the four phase mixture of ferrite, C3A(ss), C3S(ss) and C2S(ss), being free from the nucleation of Ca12Al14O33 solid solution. DEWEY : 620.13 ISSN : 0008-8846 En ligne : http://www.sciencedirect.com/science?_ob=PublicationURL&_tockey=%23TOC%235562%23 [...]

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