Low-pressure catalytic wet air oxidation of aniline over Co3O4/CeO21 / Ersoz, Gulin in Industrial & engineering chemistry research, Vol. 49 N° 4 (Fevrier 2010)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 49 N° 4 (Fevrier 2010) . - pp 1625–1630 Titre : Low-pressure catalytic wet air oxidation of aniline over Co3O4/CeO21 Type de document : texte imprimé Auteurs : Ersoz, Gulin, Auteur ; Atalay, Suheyda, Auteur Année de publication : 2010 Article en page(s) : pp 1625–1630 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Catalytic Oxidation Electron microscope X-ray diffraction Thermogravimetric analysi. Résumé : Low -pressure catalytic wet air oxidation of aniline was investigated in a bubble reactor over Co3O4 (10% wt)/CeO2. The catalyst was prepared by sol−gel technology and characterized by using scanning electron microscope, X-ray diffraction, nitrogen adsorption, and thermogravimetric analysis techniques. The aim was to search for the conditions to destroy the aniline content by avoiding production of byproducts such as ammonium, nitrate, and nitrite ions. The reaction was optimized at 0.5 g/L catalyst loading at 150 °C with a pressure of 4 atm, in 2 h with an air flow rate of 1.36 L/min. A 35.15% amount of aniline was removed, and 14% of the input nitrogen was converted into N2 gas. To evaluate the stability of the catalyst, two consecutive runs were performed by reusing the catalyst recovered. The highest removal with the reused catalyst was found as 34.94%, showing that Co3O4/CeO2 is a stable catalyst. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie901383e [article] Low-pressure catalytic wet air oxidation of aniline over Co3O4/CeO21 [texte imprimé] / Ersoz, Gulin, Auteur ; Atalay, Suheyda, Auteur . - 2010 . - pp 1625–1630. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 4 (Fevrier 2010) . - pp 1625–1630 Mots-clés : Catalytic Oxidation Electron microscope X-ray diffraction Thermogravimetric analysi. Résumé : Low -pressure catalytic wet air oxidation of aniline was investigated in a bubble reactor over Co3O4 (10% wt)/CeO2. The catalyst was prepared by sol−gel technology and characterized by using scanning electron microscope, X-ray diffraction, nitrogen adsorption, and thermogravimetric analysis techniques. The aim was to search for the conditions to destroy the aniline content by avoiding production of byproducts such as ammonium, nitrate, and nitrite ions. The reaction was optimized at 0.5 g/L catalyst loading at 150 °C with a pressure of 4 atm, in 2 h with an air flow rate of 1.36 L/min. A 35.15% amount of aniline was removed, and 14% of the input nitrogen was converted into N2 gas. To evaluate the stability of the catalyst, two consecutive runs were performed by reusing the catalyst recovered. The highest removal with the reused catalyst was found as 34.94%, showing that Co3O4/CeO2 is a stable catalyst. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie901383e

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