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Thermodynamics of binary and ternary solutions of multivalent electrolytes with formation of 1:1 and 1:2 complexes, within the mean spherical approximation / Torres-Arenas, José in Industrial & engineering chemistry research, Vol. 49 N° 4 (Fevrier 2010) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 49 N° 4 (Fevrier 2010) . - pp 1937–1946 Titre : Thermodynamics of binary and ternary solutions of multivalent electrolytes with formation of 1:1 and 1:2 complexes, within the mean spherical approximation Type de document : texte imprimé Auteurs : Torres-Arenas, José, Auteur ; Simonin, Jean-Pierre, Auteur ; Olivier Bernard, Auteur Année de publication : 2010 Article en page(s) : pp 1937–1946 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Thermodynamics  Binary  ternary  solutions  Electrolytes. Résumé : The mean activity (γ±) and osmotic (Φ) coefficients for binary and ternary aqueous solutions of trivalent electrolytes (mainly made up of lanthanide salts) are described in the framework of the primitive model of ionic solutions, using the binding mean spherical approximation (BiMSA). This model, based on the Wertheim formalism, accounts for (chemical or electrostatic) association of ions. In this work, the multivalent cation and the anion are allowed to form 1:1 (pairs) and 1:2 (trimers) complexes. Expressions for γ± and Φ are given which satisfy the Gibbs−Duhem relation. The model involves concentration-dependent cation size and effective relative permittivity, variations that can be interpreted in terms of solvent effects. The theory is applied to aqueous solutions of binary and ternary mixtures at 25 °C with common anion. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie901323x [article] Thermodynamics of binary and ternary solutions of multivalent electrolytes with formation of 1:1 and 1:2 complexes, within the mean spherical approximation [texte imprimé] / Torres-Arenas, José, Auteur ; Simonin, Jean-Pierre, Auteur ; Olivier Bernard, Auteur . - 2010 . - pp 1937–1946. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 4 (Fevrier 2010) . - pp 1937–1946 Mots-clés : Thermodynamics  Binary  ternary  solutions  Electrolytes. Résumé : The mean activity (γ±) and osmotic (Φ) coefficients for binary and ternary aqueous solutions of trivalent electrolytes (mainly made up of lanthanide salts) are described in the framework of the primitive model of ionic solutions, using the binding mean spherical approximation (BiMSA). This model, based on the Wertheim formalism, accounts for (chemical or electrostatic) association of ions. In this work, the multivalent cation and the anion are allowed to form 1:1 (pairs) and 1:2 (trimers) complexes. Expressions for γ± and Φ are given which satisfy the Gibbs−Duhem relation. The model involves concentration-dependent cation size and effective relative permittivity, variations that can be interpreted in terms of solvent effects. The theory is applied to aqueous solutions of binary and ternary mixtures at 25 °C with common anion. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie901323x