[article]
Titre : |
Regeneration of coked al-promoted sulfated zirconia catalysts by high pressure hydrogen |
Type de document : |
texte imprimé |
Auteurs : |
Yang, Ying-Chieh, Auteur ; Hung-Shan Weng, Auteur |
Année de publication : |
2010 |
Article en page(s) : |
pp 1982–1985 |
Note générale : |
Chimie industrielle |
Langues : |
Anglais (eng) |
Mots-clés : |
Catalysts High Pressure Hydrogen. |
Résumé : |
To avoid the inconvenience and danger caused by using air or oxygen as a regenerating gas for coked catalysts, this work proposes an effective regeneration method for the fouled Al-promoted sulfated zirconia (AL/SZ) catalyst. This work tries hydrogen for regenerating fouled catalysts; nevertheless, regaining activity is low when introducing atmospheric hydrogen as a regenerating gas. Fortunately, over 98% of original activity can be regained using high pressure hydrogen (2.1 MPa) at 250 °C within 8 h. The operation temperature for this new regeneration method is much lower than that for conventional methods using air or oxygen as a regenerating gas. This method does not affect the product distribution of n-C4 isomerization. |
DEWEY : |
660 |
ISSN : |
0888-5885 |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie900338b |
in Industrial & engineering chemistry research > Vol. 49 N° 4 (Fevrier 2010) . - pp 1982–1985
[article] Regeneration of coked al-promoted sulfated zirconia catalysts by high pressure hydrogen [texte imprimé] / Yang, Ying-Chieh, Auteur ; Hung-Shan Weng, Auteur . - 2010 . - pp 1982–1985. Chimie industrielle Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 49 N° 4 (Fevrier 2010) . - pp 1982–1985
Mots-clés : |
Catalysts High Pressure Hydrogen. |
Résumé : |
To avoid the inconvenience and danger caused by using air or oxygen as a regenerating gas for coked catalysts, this work proposes an effective regeneration method for the fouled Al-promoted sulfated zirconia (AL/SZ) catalyst. This work tries hydrogen for regenerating fouled catalysts; nevertheless, regaining activity is low when introducing atmospheric hydrogen as a regenerating gas. Fortunately, over 98% of original activity can be regained using high pressure hydrogen (2.1 MPa) at 250 °C within 8 h. The operation temperature for this new regeneration method is much lower than that for conventional methods using air or oxygen as a regenerating gas. This method does not affect the product distribution of n-C4 isomerization. |
DEWEY : |
660 |
ISSN : |
0888-5885 |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie900338b |
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