[article]
Titre : |
Enhanced convective heat transfer in nongas generating nanoparticle thermites |
Type de document : |
texte imprimé |
Auteurs : |
S. W. Dean, Auteur ; M. L. Pantoya, Auteur ; A. E. Gash, Auteur |
Année de publication : |
2010 |
Article en page(s) : |
pp.[111201-1/7] |
Note générale : |
Physique |
Langues : |
Anglais (eng) |
Mots-clés : |
Nanocomposites Enhanced convection reaction mechanisms Nano-alumium Thermites CuO NiO Peak pressures Flame speeds DSC TGA XRD Gas generation propagation |
Index. décimale : |
536 Chaleur. Thermodynamique |
Résumé : |
Flame propagation and peak pressure measurements were taken of two nanoscaled thermites using aluminum (Al) fuel and copper oxide (CuO) or nickel oxide (NiO) oxidizers in a confined flame tube apparatus. Thermal equilibrium simulations predict that the Al+CuO reaction exhibits high gas generation and, thus, high convective flame propagation rates while the Al+NiO reaction produces little to no gas and, therefore, should exhibit much lower flame propagation rates. Results show flame propagation rates ranged between 200 m/s and 600 m/s and peak pressures ranged between 1.7 MPa and 3.7 MPa for both composites. These results were significantly higher than expected for the Al+NiO, which generates virtually no gas. For nanometric Al particles, oxidation has recently been described by a melt-dispersion oxidation mechanism that involves a dispersion of high velocity alumina shell fragments and molten Al droplets that promote a pressure build-up by inducing a bulk movement of fluid. This mechanism unique to nanoparticle reaction may promote convection without the need for additional gas generation.
|
DEWEY : |
536 |
ISSN : |
0022-1481 |
En ligne : |
http://asmedl.aip.org/vsearch/servlet/VerityServlet?KEY=JHTRAO&ONLINE=YES&smode= [...] |
in Journal of heat transfer > Vol. 132 N° 11 (Novembre 2010) . - pp.[111201-1/7]
[article] Enhanced convective heat transfer in nongas generating nanoparticle thermites [texte imprimé] / S. W. Dean, Auteur ; M. L. Pantoya, Auteur ; A. E. Gash, Auteur . - 2010 . - pp.[111201-1/7]. Physique Langues : Anglais ( eng) in Journal of heat transfer > Vol. 132 N° 11 (Novembre 2010) . - pp.[111201-1/7]
Mots-clés : |
Nanocomposites Enhanced convection reaction mechanisms Nano-alumium Thermites CuO NiO Peak pressures Flame speeds DSC TGA XRD Gas generation propagation |
Index. décimale : |
536 Chaleur. Thermodynamique |
Résumé : |
Flame propagation and peak pressure measurements were taken of two nanoscaled thermites using aluminum (Al) fuel and copper oxide (CuO) or nickel oxide (NiO) oxidizers in a confined flame tube apparatus. Thermal equilibrium simulations predict that the Al+CuO reaction exhibits high gas generation and, thus, high convective flame propagation rates while the Al+NiO reaction produces little to no gas and, therefore, should exhibit much lower flame propagation rates. Results show flame propagation rates ranged between 200 m/s and 600 m/s and peak pressures ranged between 1.7 MPa and 3.7 MPa for both composites. These results were significantly higher than expected for the Al+NiO, which generates virtually no gas. For nanometric Al particles, oxidation has recently been described by a melt-dispersion oxidation mechanism that involves a dispersion of high velocity alumina shell fragments and molten Al droplets that promote a pressure build-up by inducing a bulk movement of fluid. This mechanism unique to nanoparticle reaction may promote convection without the need for additional gas generation.
|
DEWEY : |
536 |
ISSN : |
0022-1481 |
En ligne : |
http://asmedl.aip.org/vsearch/servlet/VerityServlet?KEY=JHTRAO&ONLINE=YES&smode= [...] |
|