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Organic substances as inhibitors for chloride-induced corrosion in reinforced concrete / M. Ormellese in Materials and corrosion, Vol. 62 N° 2 (Fevrier 2011) 

Public ISBD [article]  in Materials and corrosion > Vol. 62 N° 2 (Fevrier 2011) . - pp. 170–177 Titre : Organic substances as inhibitors for chloride-induced corrosion in reinforced concrete Type de document : texte imprimé Auteurs : M. Ormellese, Auteur ; F. Bolzoni, Auteur ; L. Lazzari, Auteur Année de publication : 2011 Article en page(s) : pp. 170–177 Note générale : Génie Mécanique Langues : Anglais (eng) Mots-clés : Chloride-induced  corrosion  Concrete  Critical  chloride  threshold  Inhibitor Index. décimale : 620.1 Essais des matériaux. Défauts des matériaux. Protection des matériaux Résumé : Corrosion inhibitors are used to prevent chloride-induced corrosion in reinforced concrete structures. Since performance of commercial organic inhibitors is only partially satisfactory, a 7-year long research has been carried out in order to set-up a new organic inhibitive mixture, able to prevent chlorides-induced corrosion. A first screening, by means of potentiodynamic polarisation test in alkaline synthetic pore solution, was performed on 80 organic compounds, mainly primary and tertiary amines, aminoalcohols, carboxylates compounds and aminoacids, in order to select the best inhibiting substances. The nine best inhibitive organic substances were selected for long-term tests: 2 amines (dimethylethanolamine and triethylentetramine), 4 aminoacids (aspartate, asparagine, glutamate and glutamine) and 3 carboxylates compounds (tartrate, benzoate and EDTA). Potentiostatic polarisation and free corrosion tests in synthetic pore solution were performed, as well as tests in concrete exposed to accelerated chlorides penetration. Five years of tests allow estimating the efficiency of the substances in preventing chlorides-induced corrosion, in term of influence on chlorides penetration and on critical chlorides threshold. DEWEY : 620.1 ISSN : 0947-5117 En ligne : http://onlinelibrary.wiley.com/doi/10.1002/maco.201005763/abstract [article] Organic substances as inhibitors for chloride-induced corrosion in reinforced concrete [texte imprimé] / M. Ormellese, Auteur ; F. Bolzoni, Auteur ; L. Lazzari, Auteur . - 2011 . - pp. 170–177. Génie Mécanique Langues : Anglais (eng) in Materials and corrosion > Vol. 62 N° 2 (Fevrier 2011) . - pp. 170–177 Mots-clés : Chloride-induced  corrosion  Concrete  Critical  chloride  threshold  Inhibitor Index. décimale : 620.1 Essais des matériaux. Défauts des matériaux. Protection des matériaux Résumé : Corrosion inhibitors are used to prevent chloride-induced corrosion in reinforced concrete structures. Since performance of commercial organic inhibitors is only partially satisfactory, a 7-year long research has been carried out in order to set-up a new organic inhibitive mixture, able to prevent chlorides-induced corrosion. A first screening, by means of potentiodynamic polarisation test in alkaline synthetic pore solution, was performed on 80 organic compounds, mainly primary and tertiary amines, aminoalcohols, carboxylates compounds and aminoacids, in order to select the best inhibiting substances. The nine best inhibitive organic substances were selected for long-term tests: 2 amines (dimethylethanolamine and triethylentetramine), 4 aminoacids (aspartate, asparagine, glutamate and glutamine) and 3 carboxylates compounds (tartrate, benzoate and EDTA). Potentiostatic polarisation and free corrosion tests in synthetic pore solution were performed, as well as tests in concrete exposed to accelerated chlorides penetration. Five years of tests allow estimating the efficiency of the substances in preventing chlorides-induced corrosion, in term of influence on chlorides penetration and on critical chlorides threshold. DEWEY : 620.1 ISSN : 0947-5117 En ligne : http://onlinelibrary.wiley.com/doi/10.1002/maco.201005763/abstract