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330Cb alloy (Fe-35Ni-18Cr-1Nb-2Si) oxidation study between 800 and 1000 °C / C. Issartel in Materials and corrosion, Vol. 61 N° 11 (Novembre 2010) 

Public ISBD [article]  in Materials and corrosion > Vol. 61 N° 11 (Novembre 2010) . - pp. 929–938 Titre : 330Cb alloy (Fe-35Ni-18Cr-1Nb-2Si) oxidation study between 800 and 1000 °C Type de document : texte imprimé Auteurs : C. Issartel, Auteur ; H. Buscail, Auteur ; C. T. Nguyen, Auteur Année de publication : 2011 Article en page(s) : pp. 929–938 Note générale : Génie mécanique Langues : Anglais (eng) Mots-clés : 330Cb;  conveyor  units;Fe-35Ni-18Cr-1Nb-2Si;  high  temperatures;  in  situ  XRD;  Niobium;  oxidation;  silicon Résumé : The 330Cb alloy (Fe-35Ni-18Cr-1Nb-2Si) has been oxidized, in air, in the 800–1000 °C temperature range. Results show the formation of a chromia layer acting as a good diffusion barrier under isothermal conditions. Nevertheless, some oxide scale spallation is generally observed after cooling to room temperature. A fine and adherent chromia scale is only obtained after short-term oxidation at 800 °C. In this case, the scale is probably too fine to expect a protection against carburization. At 900 °C we have observed that the scale spalled off on the niobium rich alloy areas. At 1000 °C the scale adherence is very bad. This study shows that the oxide scale adherence is decreased when the 330Cb alloy oxidation duration is increased. En ligne : http://onlinelibrary.wiley.com/doi/10.1002/maco.200905442/abstract [article] 330Cb alloy (Fe-35Ni-18Cr-1Nb-2Si) oxidation study between 800 and 1000 °C [texte imprimé] / C. Issartel, Auteur ; H. Buscail, Auteur ; C. T. Nguyen, Auteur . - 2011 . - pp. 929–938. Génie mécanique Langues : Anglais (eng) in Materials and corrosion > Vol. 61 N° 11 (Novembre 2010) . - pp. 929–938 Mots-clés : 330Cb;  conveyor  units;Fe-35Ni-18Cr-1Nb-2Si;  high  temperatures;  in  situ  XRD;  Niobium;  oxidation;  silicon Résumé : The 330Cb alloy (Fe-35Ni-18Cr-1Nb-2Si) has been oxidized, in air, in the 800–1000 °C temperature range. Results show the formation of a chromia layer acting as a good diffusion barrier under isothermal conditions. Nevertheless, some oxide scale spallation is generally observed after cooling to room temperature. A fine and adherent chromia scale is only obtained after short-term oxidation at 800 °C. In this case, the scale is probably too fine to expect a protection against carburization. At 900 °C we have observed that the scale spalled off on the niobium rich alloy areas. At 1000 °C the scale adherence is very bad. This study shows that the oxide scale adherence is decreased when the 330Cb alloy oxidation duration is increased. En ligne : http://onlinelibrary.wiley.com/doi/10.1002/maco.200905442/abstract

Oxidation mechanism of the Inconel 601 alloy at high temperatures / H. Buscail in Materials and corrosion, Vol. 62 N° 5 (Mai 2011) 

Public ISBD [article]  in Materials and corrosion > Vol. 62 N° 5 (Mai 2011) . - pp. 416–422 Titre : Oxidation mechanism of the Inconel 601 alloy at high temperatures Type de document : texte imprimé Auteurs : H. Buscail, Auteur ; S. Perrier, Auteur ; C. Josse, Auteur Année de publication : 2011 Article en page(s) : pp. 416–422 Note générale : Génie Mécanique Langues : Anglais (eng) Mots-clés : Aluminum  Cr2O3  Inconel  601  Nickel-base  superalloy  OxidationTitanium  X-ray  diffraction  (XRD) Index. décimale : 620.1 Essais des matériaux. Défauts des matériaux. Protection des matériaux Résumé : The Inconel 601 alloy oxidation was performed in air, in the temperature range 1000–1150 °C, during 90 h. Kinetic results show that the parabolic behavior is always followed in this temperature range. The Arrhenius plot of the kp values shows two different activation energies. Between 1000 and 1050 °C the activation energy is Ea1 = 160 ± 10 kJ/mol. In the 1050–1150 °C temperature range a higher value is calculated Ea2 = 252 ± 20 kJ/mol. The Ea2 value and the X-ray diffraction (XRD) results and scanning electron microscope (SEM) energy dispersive X-ray spectroscopy (EDS) examinations are in accordance with a scale growth mechanism limited by a growing Cr2O3 scale acting as a diffusion barrier. In the 1000–1050 °C temperature range the activation energy is lower and the structural analyses show that the oxide scale is not only composed of Cr2O3. Then, the oxide scale is composed of titanium oxides (TiO2 and Ti2Cr7O17) and chromia mixed together. A doping effect of the chromia scale by titanium can be envisaged. Our results also show the presence of some Mn1.5Cr1.5O4 at the external interface. This external subscale spalls off easily during cooling after the highest temperature oxidation tests. Nevertheless, XRD results and SEM–EDS observations show that the Cr2O3 scale remains very adherent on the substrate and can give a good oxidation protection. This good adherence can be related to the presence of a low amount of aluminum in the Inconel 601 alloy composition. DEWEY : 620.1 ISSN : 0947-5117 En ligne : http://onlinelibrary.wiley.com/doi/10.1002/maco.200905519/abstract [article] Oxidation mechanism of the Inconel 601 alloy at high temperatures [texte imprimé] / H. Buscail, Auteur ; S. Perrier, Auteur ; C. Josse, Auteur . - 2011 . - pp. 416–422. Génie Mécanique Langues : Anglais (eng) in Materials and corrosion > Vol. 62 N° 5 (Mai 2011) . - pp. 416–422 Mots-clés : Aluminum  Cr2O3  Inconel  601  Nickel-base  superalloy  OxidationTitanium  X-ray  diffraction  (XRD) Index. décimale : 620.1 Essais des matériaux. Défauts des matériaux. Protection des matériaux Résumé : The Inconel 601 alloy oxidation was performed in air, in the temperature range 1000–1150 °C, during 90 h. Kinetic results show that the parabolic behavior is always followed in this temperature range. The Arrhenius plot of the kp values shows two different activation energies. Between 1000 and 1050 °C the activation energy is Ea1 = 160 ± 10 kJ/mol. In the 1050–1150 °C temperature range a higher value is calculated Ea2 = 252 ± 20 kJ/mol. The Ea2 value and the X-ray diffraction (XRD) results and scanning electron microscope (SEM) energy dispersive X-ray spectroscopy (EDS) examinations are in accordance with a scale growth mechanism limited by a growing Cr2O3 scale acting as a diffusion barrier. In the 1000–1050 °C temperature range the activation energy is lower and the structural analyses show that the oxide scale is not only composed of Cr2O3. Then, the oxide scale is composed of titanium oxides (TiO2 and Ti2Cr7O17) and chromia mixed together. A doping effect of the chromia scale by titanium can be envisaged. Our results also show the presence of some Mn1.5Cr1.5O4 at the external interface. This external subscale spalls off easily during cooling after the highest temperature oxidation tests. Nevertheless, XRD results and SEM–EDS observations show that the Cr2O3 scale remains very adherent on the substrate and can give a good oxidation protection. This good adherence can be related to the presence of a low amount of aluminum in the Inconel 601 alloy composition. DEWEY : 620.1 ISSN : 0947-5117 En ligne : http://onlinelibrary.wiley.com/doi/10.1002/maco.200905519/abstract