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Behaviour of ferritic stainless steels subjected to dry biogas atmospheres at high temperatures / P. Promdirek in Materials and corrosion, Vol. 62 N° 7 (Juillet 2011) 

Public ISBD [article]  in Materials and corrosion > Vol. 62 N° 7 (Juillet 2011) . - pp. 616–622 Titre : Behaviour of ferritic stainless steels subjected to dry biogas atmospheres at high temperatures Type de document : texte imprimé Auteurs : P. Promdirek, Auteur ; G. Lothongkhum, Auteur ; S. Chandra-ambhorn, Auteur Année de publication : 2011 Article en page(s) : pp. 616–622 Note générale : Génie Mécanique Langues : Anglais (eng) Mots-clés : SOFC  Ferritic  stainless  steels  Biogas  Oxidation  Carburization Index. décimale : 620.1 Essais des matériaux. Défauts des matériaux. Protection des matériaux Résumé : The objective of this study is to understand the high temperature corrosion behaviour of the ferritic stainless steel type AISI 441 (18CrTiNb), a candidate for SOFC interconnectors, under dry synthetic fermentation biogas (CH4 + CO2 mixtures), possibly used at the anode side of the cell. Thermodynamic analysis showed that, in such mixtures, the partial pressure of oxygen lies in the range of 10−23 to 10−20 bar for temperature between 700 and 900 °C and that the formation of solid carbon may take place in several conditions. XRD results confirmed the formation of Cr2O3 and Mn-Cr spinel, with a mixture of internal carbides. In this temperature range, kinetic experiments showed linear mass change. Comparing with the linear rate constants of 441 oxidised in pure CO2, corrosion in biogas was larger and increased with increasing the methane content in the biogas. The surface morphology of the corroded specimens showed a dense oxide scale at temperatures less than 800 °C, serving as an efficient barrier to carbon penetration. However, when the temperature reaches 900 °C, cracks and pores appear in the oxide scale, carbon can precipitate and diffuse easier than at 800 °C and may lead to internal carbide formation. In such biogas atmospheres, 800 °C seems the maximum operating temperature of devices containing this ferritic stainless steel. DEWEY : 620.1 ISSN : 0947-5117 En ligne : http://onlinelibrary.wiley.com/doi/10.1002/maco.201005878/abstract [article] Behaviour of ferritic stainless steels subjected to dry biogas atmospheres at high temperatures [texte imprimé] / P. Promdirek, Auteur ; G. Lothongkhum, Auteur ; S. Chandra-ambhorn, Auteur . - 2011 . - pp. 616–622. Génie Mécanique Langues : Anglais (eng) in Materials and corrosion > Vol. 62 N° 7 (Juillet 2011) . - pp. 616–622 Mots-clés : SOFC  Ferritic  stainless  steels  Biogas  Oxidation  Carburization Index. décimale : 620.1 Essais des matériaux. Défauts des matériaux. Protection des matériaux Résumé : The objective of this study is to understand the high temperature corrosion behaviour of the ferritic stainless steel type AISI 441 (18CrTiNb), a candidate for SOFC interconnectors, under dry synthetic fermentation biogas (CH4 + CO2 mixtures), possibly used at the anode side of the cell. Thermodynamic analysis showed that, in such mixtures, the partial pressure of oxygen lies in the range of 10−23 to 10−20 bar for temperature between 700 and 900 °C and that the formation of solid carbon may take place in several conditions. XRD results confirmed the formation of Cr2O3 and Mn-Cr spinel, with a mixture of internal carbides. In this temperature range, kinetic experiments showed linear mass change. Comparing with the linear rate constants of 441 oxidised in pure CO2, corrosion in biogas was larger and increased with increasing the methane content in the biogas. The surface morphology of the corroded specimens showed a dense oxide scale at temperatures less than 800 °C, serving as an efficient barrier to carbon penetration. However, when the temperature reaches 900 °C, cracks and pores appear in the oxide scale, carbon can precipitate and diffuse easier than at 800 °C and may lead to internal carbide formation. In such biogas atmospheres, 800 °C seems the maximum operating temperature of devices containing this ferritic stainless steel. DEWEY : 620.1 ISSN : 0947-5117 En ligne : http://onlinelibrary.wiley.com/doi/10.1002/maco.201005878/abstract