Synthesis of selected vinylimidazolium ionic liquids and their effectiveness as corrosion inhibitors for carbon steel in aqueous sulfuric acid / Diego Guzman - Lucero in Industrial & engineering chemistry research, Vol. 50 N° 12 (Juin 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 12 (Juin 2011) . - pp. 7129-7140 Titre : Synthesis of selected vinylimidazolium ionic liquids and their effectiveness as corrosion inhibitors for carbon steel in aqueous sulfuric acid Type de document : texte imprimé Auteurs : Diego Guzman - Lucero, Auteur ; Octavio Olivares - Xometl, Auteur ; Rafael Martinez - Palou, Auteur Année de publication : 2011 Article en page(s) : pp. 7129-7140 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Carbon steel Corrosion inhibitor Ionic liquid Résumé : ive imidazolium-type ionic liquids, containing both N 1 unsaturated and N3 long alkyl saturated chains as cations and bromide as anion (IL1―IL5), were obtained by conventional and microwave synthesis. Compounds were tested in aqueous 1 M H2SO4 as corrosion inhibitors for carbon steel. Weight loss and polarization curves indicated that inhibition efficiency increased with concentration, which turns out to be dependent on alkyl chain size linked to N3 (IL4 > IL3 > IL1 > IL2 > IL5). The relatively high inhibitory properties (88―95%) displayed by IL4 within 25―40 °C were ascribed to a chemisorption process that involved the following: the adsorption of protonated imidazolium molecules on both the anodic and cathodic sites, the latter in competition with hydrogen ions to mitigate hydrogen evolution; and also the formation of π bond with iron by the C=N group from imidazolium ring (this way inhibitor produced more than one center of adsorption action). Surface analysis indicated a considerable reduction of corrosion products after the addition of IL4. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24239026 [article] Synthesis of selected vinylimidazolium ionic liquids and their effectiveness as corrosion inhibitors for carbon steel in aqueous sulfuric acid [texte imprimé] / Diego Guzman - Lucero, Auteur ; Octavio Olivares - Xometl, Auteur ; Rafael Martinez - Palou, Auteur . - 2011 . - pp. 7129-7140. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 12 (Juin 2011) . - pp. 7129-7140 Mots-clés : Carbon steel Corrosion inhibitor Ionic liquid Résumé : ive imidazolium-type ionic liquids, containing both N 1 unsaturated and N3 long alkyl saturated chains as cations and bromide as anion (IL1―IL5), were obtained by conventional and microwave synthesis. Compounds were tested in aqueous 1 M H2SO4 as corrosion inhibitors for carbon steel. Weight loss and polarization curves indicated that inhibition efficiency increased with concentration, which turns out to be dependent on alkyl chain size linked to N3 (IL4 > IL3 > IL1 > IL2 > IL5). The relatively high inhibitory properties (88―95%) displayed by IL4 within 25―40 °C were ascribed to a chemisorption process that involved the following: the adsorption of protonated imidazolium molecules on both the anodic and cathodic sites, the latter in competition with hydrogen ions to mitigate hydrogen evolution; and also the formation of π bond with iron by the C=N group from imidazolium ring (this way inhibitor produced more than one center of adsorption action). Surface analysis indicated a considerable reduction of corrosion products after the addition of IL4. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24239026

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