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Adsorptive removal of as(III) from aqueous solution by zr(IV)-loaded collagen fiber / Xin Huang in Industrial & engineering chemistry research, Vol. 47 n°15 (Août 2008) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 47 n°15 (Août 2008) . - p. 5623-5628 Titre : Adsorptive removal of as(III) from aqueous solution by zr(IV)-loaded collagen fiber Type de document : texte imprimé Auteurs : Xin Huang, Auteur ; Limin Jiao, Auteur ; Xuepin Liao, Auteur Année de publication : 2008 Article en page(s) : p. 5623-5628 Note générale : Bibliogr. p. 5627-5628 Langues : Anglais (eng) Mots-clés : Arsenite  (III);  ZrCF;  Adsorption Résumé : Compared with arsenate [As(V)], arsenite [As(III)] is more toxic to human health and more difficult to be removed from aqueous solution. In this study, a novel adsorbent, Zr(IV)-loaded collagen fiber (ZrCF), was prepared, and its adsorption characteristics to As(III) were investigated. It was found that ZrCF can effectively remove As(III) from aqueous solution in the pH range of 9.0-12.0. The maximum adsorption capacity of As(III) by ZrCF reached up to 54.02 mg As/g when the initial concentration of As(III) was 73.00 mg/L at 303 K and pH 11.0. The adsorption isotherms of ZrCF to As(III) were well fitted by the Langmuir-Freundlich equation. The adsorption kinetic experimental data were well described by the pseudo-second-order rate equation, and the calculated adsorption capacities were close to those obtained by experiments. The leakage of zirconium loaded on ZrCF was negligible during adsorption process. Therefore, this study indicates that ZrCF is a promising adsorbent for As(III) removal from aqueous solution. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie071608k [article] Adsorptive removal of as(III) from aqueous solution by zr(IV)-loaded collagen fiber [texte imprimé] / Xin Huang, Auteur ; Limin Jiao, Auteur ; Xuepin Liao, Auteur . - 2008 . - p. 5623-5628. Bibliogr. p. 5627-5628 Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 n°15 (Août 2008) . - p. 5623-5628 Mots-clés : Arsenite  (III);  ZrCF;  Adsorption Résumé : Compared with arsenate [As(V)], arsenite [As(III)] is more toxic to human health and more difficult to be removed from aqueous solution. In this study, a novel adsorbent, Zr(IV)-loaded collagen fiber (ZrCF), was prepared, and its adsorption characteristics to As(III) were investigated. It was found that ZrCF can effectively remove As(III) from aqueous solution in the pH range of 9.0-12.0. The maximum adsorption capacity of As(III) by ZrCF reached up to 54.02 mg As/g when the initial concentration of As(III) was 73.00 mg/L at 303 K and pH 11.0. The adsorption isotherms of ZrCF to As(III) were well fitted by the Langmuir-Freundlich equation. The adsorption kinetic experimental data were well described by the pseudo-second-order rate equation, and the calculated adsorption capacities were close to those obtained by experiments. The leakage of zirconium loaded on ZrCF was negligible during adsorption process. Therefore, this study indicates that ZrCF is a promising adsorbent for As(III) removal from aqueous solution. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie071608k

Preparation of strong cationic chitosan-graft-polyacrylamide flocculants and their flocculating properties / Yaobo Lu in Industrial & engineering chemistry research, Vol. 50 N° 12 (Juin 2011) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 50 N° 12 (Juin 2011) . - pp. 7141-7149 Titre : Preparation of strong cationic chitosan-graft-polyacrylamide flocculants and their flocculating properties Type de document : texte imprimé Auteurs : Yaobo Lu, Auteur ; Yabo Shang, Auteur ; Xin Huang, Auteur Année de publication : 2011 Article en page(s) : pp. 7141-7149 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Flocculation  reagent  Preparation Résumé : Recently, more attentions have been paid to natural polymer-based flocculants in water treatment, since they are believed to be low-cost, nontoxic, and environmentally friendly materials. In this work, strong cationic chitosan-based graft copolymer flocculants (3-chloro-2-hydroxypropyl trimethyl ammonium chloride (CTA) modified chitosan-graft-polyacrylamide, denoted as chitosan-CTA-g-PAM) have been prepared, and their flocculating properties were studied systematically, both at the laboratory scale and at the pilot scale. In laboratory scale, a kaolin suspension was employed as synthetic wastewater. The effects of dosage, temperature, and original turbidity of untreated wastewater were investigated, respectively. Moreover, in pilot scale, the raw water from the Zhenjiang part of the Yangtse River in China was used as wastewater. The influences of three external factors-dosage, sedimentation time, and mechanical mixing rate-on the flocculating performances have been studied by orthogonal testing, respectively. The experimental results in pilot scale were fairly consistent with those from the beaker experiment in laboratory scale. In comparison with polyferric sulfate, which is the flocculant currently used by the Zhenjiang Water Supply Company, chitosan-CTA-g-PAM showed better flocculating properties. Meanwhile, the effect of the degree of substitution of CTA on the flocculating properties has been also studied, both at the laboratory scale and at the pilot scale. It was indicated that chitosan-CTA-g-PAM with higher cationic degree had better flocculating performances, which was also confirmed by the flocculation kinetics analysis. Furthermore, the flocculation mechanisms of chitosan-CTA-g-PAM have been discussed in detail. Above all, the flocculating experiments in laboratory and pilot scales both indicated that chitosan-CTA-g-PAM showed good flocculating performances in water treatment. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24239027 [article] Preparation of strong cationic chitosan-graft-polyacrylamide flocculants and their flocculating properties [texte imprimé] / Yaobo Lu, Auteur ; Yabo Shang, Auteur ; Xin Huang, Auteur . - 2011 . - pp. 7141-7149. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 12 (Juin 2011) . - pp. 7141-7149 Mots-clés : Flocculation  reagent  Preparation Résumé : Recently, more attentions have been paid to natural polymer-based flocculants in water treatment, since they are believed to be low-cost, nontoxic, and environmentally friendly materials. In this work, strong cationic chitosan-based graft copolymer flocculants (3-chloro-2-hydroxypropyl trimethyl ammonium chloride (CTA) modified chitosan-graft-polyacrylamide, denoted as chitosan-CTA-g-PAM) have been prepared, and their flocculating properties were studied systematically, both at the laboratory scale and at the pilot scale. In laboratory scale, a kaolin suspension was employed as synthetic wastewater. The effects of dosage, temperature, and original turbidity of untreated wastewater were investigated, respectively. Moreover, in pilot scale, the raw water from the Zhenjiang part of the Yangtse River in China was used as wastewater. The influences of three external factors-dosage, sedimentation time, and mechanical mixing rate-on the flocculating performances have been studied by orthogonal testing, respectively. The experimental results in pilot scale were fairly consistent with those from the beaker experiment in laboratory scale. In comparison with polyferric sulfate, which is the flocculant currently used by the Zhenjiang Water Supply Company, chitosan-CTA-g-PAM showed better flocculating properties. Meanwhile, the effect of the degree of substitution of CTA on the flocculating properties has been also studied, both at the laboratory scale and at the pilot scale. It was indicated that chitosan-CTA-g-PAM with higher cationic degree had better flocculating performances, which was also confirmed by the flocculation kinetics analysis. Furthermore, the flocculation mechanisms of chitosan-CTA-g-PAM have been discussed in detail. Above all, the flocculating experiments in laboratory and pilot scales both indicated that chitosan-CTA-g-PAM showed good flocculating performances in water treatment. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24239027