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Application of bifunctional ionic liquid extractants [A336][CA-12] and [A336][CA-100] to the lanthanum extraction and separation from rare earths in the chloride medium / Wang, Wei in Industrial & engineering chemistry research, Vol. 50 N° 12 (Juin 2011) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 50 N° 12 (Juin 2011) . - pp. 7534-7541 Titre : Application of bifunctional ionic liquid extractants [A336][CA-12] and [A336][CA-100] to the lanthanum extraction and separation from rare earths in the chloride medium Type de document : texte imprimé Auteurs : Wang, Wei, Auteur ; Hualing Yang, Auteur ; Hongmin Cui, Auteur Année de publication : 2011 Article en page(s) : pp. 7534-7541 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Ionic  liquid Résumé : In this Article, bifunctional ionic liquid extractants (Bif-ILEs) tricaprylmethylammonium sec-octylphenoxy acetic acid ([A366][CA-12]) and tricaprylmethylammonium sec-nonylphenoxy acetic acid ([A336][CA-100]) used for the rare earths (REs) extraction from the chloride medium have been investigated. The effects of extractants concentration, equilibrium pH of aqueous phase, salt concentration, temperature, etc., were discussed. The results show that the extraction ability of [A336][CA-12] and [A336] [CA-100] is higher than that of the conventional extractants sec-octylphenoxy acetic acid (CA-12), sec-nonylphenoxy acetic acid (CA-100), tri-n-butyl phosphate (TBP), and di-(1-metylheptyl)methyl phosphate (P350) under the same conditions. Furthermore, in the [A336][CA-12] system, the separation factors (β) between La(III) and other REs(III) are higher than 6.0, which indicates that [A336][CA-12] would be suitable for the La(III) extraction and separation. The extraction mechanism is also proposed, and there is a similar extraction tendency in both the [A336][CA-12] and the [A336][CA-100] systems. The loaded organic phase is easy to strip; more than 95% La(III) could be stripped from the loaded organic phase when the stripping acidity is higher than 0.03 M. The recycling experiments also indicate that the two extraction systems could be recycled without loss of the extraction efficiency. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24239070 [article] Application of bifunctional ionic liquid extractants [A336][CA-12] and [A336][CA-100] to the lanthanum extraction and separation from rare earths in the chloride medium [texte imprimé] / Wang, Wei, Auteur ; Hualing Yang, Auteur ; Hongmin Cui, Auteur . - 2011 . - pp. 7534-7541. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 12 (Juin 2011) . - pp. 7534-7541 Mots-clés : Ionic  liquid Résumé : In this Article, bifunctional ionic liquid extractants (Bif-ILEs) tricaprylmethylammonium sec-octylphenoxy acetic acid ([A366][CA-12]) and tricaprylmethylammonium sec-nonylphenoxy acetic acid ([A336][CA-100]) used for the rare earths (REs) extraction from the chloride medium have been investigated. The effects of extractants concentration, equilibrium pH of aqueous phase, salt concentration, temperature, etc., were discussed. The results show that the extraction ability of [A336][CA-12] and [A336] [CA-100] is higher than that of the conventional extractants sec-octylphenoxy acetic acid (CA-12), sec-nonylphenoxy acetic acid (CA-100), tri-n-butyl phosphate (TBP), and di-(1-metylheptyl)methyl phosphate (P350) under the same conditions. Furthermore, in the [A336][CA-12] system, the separation factors (β) between La(III) and other REs(III) are higher than 6.0, which indicates that [A336][CA-12] would be suitable for the La(III) extraction and separation. The extraction mechanism is also proposed, and there is a similar extraction tendency in both the [A336][CA-12] and the [A336][CA-100] systems. The loaded organic phase is easy to strip; more than 95% La(III) could be stripped from the loaded organic phase when the stripping acidity is higher than 0.03 M. The recycling experiments also indicate that the two extraction systems could be recycled without loss of the extraction efficiency. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24239070

Recovery of trace rare earths from high - level Fe3 + and Al 3+ waste of oil shale ash (Fe - Al - OSA) / Hualing Yang in Industrial & engineering chemistry research, Vol. 49 N° 22 (Novembre 2010) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 49 N° 22 (Novembre 2010) . - pp. 11645-11651 Titre : Recovery of trace rare earths from high - level Fe3 + and Al 3+ waste of oil shale ash (Fe - Al - OSA) Type de document : texte imprimé Auteurs : Hualing Yang, Auteur ; Wang, Wei, Auteur ; Dongli Zhang, Auteur Année de publication : 2011 Article en page(s) : pp. 11645-11651 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Ash Résumé : An experimental investigation was undertaken to study the high-efficient and clean enrichment of trace rare earths from high-level Fe3+ and Al3+ waste of oil shale ash (Fe-Al-OSA). The optimum leaching temperature, ratio of solid to liquid, acidity, and reaction time for Fe-Al-OSA were 30 °C, 1:7, 50% (v/v), and 1 h by the Taguchi method, respectively, and the leaching rate of rare earths has been reached up to 96.24%. The optimal extraction conditions for removing Fe3+ from leaching liquor of Fe-Al-OSA were as follows: the organic phase was 30% N235 + 10% isooctyl alcohol (ROH) + 60% n-heptane, acidity of aqueous phase was about 3.00 mol/L, and phase ratio (Vo:Vw) was 8:5. More than 92.09% of Fe3+ was recovered by using countercurrent extraction process with 4—5 stages. The 99.76% of high pure Fe byproduct was obtained by stripping the loaded N235 organic phase, and it can be used as chemistry pure reagent directly. After adjusting the pH of the raffinate to 6.00 with MgO and saturated Na2CO3 solution, all of the Al3+ and rare earths were transformed to hydroxide precipitation and separated from the solution, together with other small amounts of coexisting metal ions such as Ca2+ and Mg2+. Then, the precipitation was washed, collected, and dissolved by HNO3. Rare earths can be separated from the solution by solvent extraction with 30% tributyl phosphate (TBP) +70% n-heptane at the phase ratio (Vo:Vw) 3:2. The recovery rate of rare earths from Fe-Al-OSA has reached 86.30% in the whole separation process. The residual Al3+ in solution was recycled. This work shows that such a treatment route is one kind of highly efficient and clean method for separating Fe3+ and Al3+, and concentrating rare earths from Fe-Al-OSA. The solid waste (Fe-Al-OSA) from the refinery can also be utilized effectively to solve the ecological and environmental problems caused by the waste heap. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23437863 [article] Recovery of trace rare earths from high - level Fe3 + and Al 3+ waste of oil shale ash (Fe - Al - OSA) [texte imprimé] / Hualing Yang, Auteur ; Wang, Wei, Auteur ; Dongli Zhang, Auteur . - 2011 . - pp. 11645-11651. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 22 (Novembre 2010) . - pp. 11645-11651 Mots-clés : Ash Résumé : An experimental investigation was undertaken to study the high-efficient and clean enrichment of trace rare earths from high-level Fe3+ and Al3+ waste of oil shale ash (Fe-Al-OSA). The optimum leaching temperature, ratio of solid to liquid, acidity, and reaction time for Fe-Al-OSA were 30 °C, 1:7, 50% (v/v), and 1 h by the Taguchi method, respectively, and the leaching rate of rare earths has been reached up to 96.24%. The optimal extraction conditions for removing Fe3+ from leaching liquor of Fe-Al-OSA were as follows: the organic phase was 30% N235 + 10% isooctyl alcohol (ROH) + 60% n-heptane, acidity of aqueous phase was about 3.00 mol/L, and phase ratio (Vo:Vw) was 8:5. More than 92.09% of Fe3+ was recovered by using countercurrent extraction process with 4—5 stages. The 99.76% of high pure Fe byproduct was obtained by stripping the loaded N235 organic phase, and it can be used as chemistry pure reagent directly. After adjusting the pH of the raffinate to 6.00 with MgO and saturated Na2CO3 solution, all of the Al3+ and rare earths were transformed to hydroxide precipitation and separated from the solution, together with other small amounts of coexisting metal ions such as Ca2+ and Mg2+. Then, the precipitation was washed, collected, and dissolved by HNO3. Rare earths can be separated from the solution by solvent extraction with 30% tributyl phosphate (TBP) +70% n-heptane at the phase ratio (Vo:Vw) 3:2. The recovery rate of rare earths from Fe-Al-OSA has reached 86.30% in the whole separation process. The residual Al3+ in solution was recycled. This work shows that such a treatment route is one kind of highly efficient and clean method for separating Fe3+ and Al3+, and concentrating rare earths from Fe-Al-OSA. The solid waste (Fe-Al-OSA) from the refinery can also be utilized effectively to solve the ecological and environmental problems caused by the waste heap. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23437863