Documents disponibles écrits par cet auteur

Improved coating window for slot coating / Chih-Ping Chin in Industrial & engineering chemistry research, Vol. 49 N° 8 (Avril 2010) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 49 N° 8 (Avril 2010) . - pp. 3802–3809 Titre : Improved coating window for slot coating Type de document : texte imprimé Auteurs : Chih-Ping Chin, Auteur ; Ho Shing Wu, Auteur ; Shaw S. Wang, Auteur Année de publication : 2010 Article en page(s) : pp. 3802–3809 Note générale : Industrial Chemistry Langues : Anglais (eng) Mots-clés : Coating  low  viscosity  with  high  viscosity Résumé : Slot die is a premetered coating operation in which the coating solution is extruded from a feed slot onto the surface of a substrate passing through. The defect-free region of operation is known as the “coating window”, and the wider it is, the more versatile the operation will be. The slot-coating experiments reported here were carried out with two types of coating solutions, a hard coating solution with low viscosity and a polysilica solution with high viscosity. The coating windows were measured as flow rates q versus minimum and maximum coating speeds, Vmin and Vmax, respectively. Therefore, at a given flow rate of the coating solution, there exists a minimum speed and a maximum speed that border the corresponding coating window, outside which coating defects occur. Also, in our experiments, the coating windows shifted to higher coating speed and obtained thinner coating film thicknesses through different settings of the die angle to the substrate and different geometries of die lips. The data showed that the coating windows shifted to higher speed and thinner film thicknesses when the die angle and the geometry of the die lips were varied appropriately. These results have important practical implications. The fundamental principles involved here are also applicable to other premetered coating processes. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie801900t [article] Improved coating window for slot coating [texte imprimé] / Chih-Ping Chin, Auteur ; Ho Shing Wu, Auteur ; Shaw S. Wang, Auteur . - 2010 . - pp. 3802–3809. Industrial Chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 8 (Avril 2010) . - pp. 3802–3809 Mots-clés : Coating  low  viscosity  with  high  viscosity Résumé : Slot die is a premetered coating operation in which the coating solution is extruded from a feed slot onto the surface of a substrate passing through. The defect-free region of operation is known as the “coating window”, and the wider it is, the more versatile the operation will be. The slot-coating experiments reported here were carried out with two types of coating solutions, a hard coating solution with low viscosity and a polysilica solution with high viscosity. The coating windows were measured as flow rates q versus minimum and maximum coating speeds, Vmin and Vmax, respectively. Therefore, at a given flow rate of the coating solution, there exists a minimum speed and a maximum speed that border the corresponding coating window, outside which coating defects occur. Also, in our experiments, the coating windows shifted to higher coating speed and obtained thinner coating film thicknesses through different settings of the die angle to the substrate and different geometries of die lips. The data showed that the coating windows shifted to higher speed and thinner film thicknesses when the die angle and the geometry of the die lips were varied appropriately. These results have important practical implications. The fundamental principles involved here are also applicable to other premetered coating processes. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie801900t

New approach to pesticide delivery using nanosuspensions / Chih-Ping Chin in Industrial & engineering chemistry research, Vol. 50 N° 12 (Juin 2011) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 50 N° 12 (Juin 2011) . - pp. 7637-7643 Titre : New approach to pesticide delivery using nanosuspensions : research and applications Type de document : texte imprimé Auteurs : Chih-Ping Chin, Auteur ; Ho-Shing Wu, Auteur ; Shaw S. Wang, Auteur Année de publication : 2011 Article en page(s) : pp. 7637-7643 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Pesticides Résumé : In pharmacology, development of a formulated nanosuspension, a potential drug delivery system for poorly soluble drugs, has been investigated to overcome the bioavailability problems caused by weak solubility, limited chemical stability following administration (i.e., a short half-life), poor bioavailability, and potentially strong side effects requiring drug enrichment at the site of action. For first time use in a pesticide delivery system, a two-step milling process for preparing a nanosuspension in a system of active compound/surfactant/water is described in this paper. First, all the components were mixed at a certain composition to prepare a microsuspension by the general milling process. Then, the microsuspension was taken into a nanomilling process with zirconium oxide beads, having a diameter range of 0.1―0.2 mm, as the milling media to generate the nanosuspension. Therefore, a nanosuspension concentrate was formed. To demonstrate the potential applications of this novel system, it was used to make a formulation with a poorly soluble crystalline insecticide, carbofuran. In a comparative study, two kinds of carbofuran formulations, a microsuspension (commercial) and a nanosuspension, were administered to a diamondback moth (DBM) to test their efficacy and stability as a pesticide. The results indicate that carbofuran has the same efficacy at a lower dose for the nanosuspension compared to the microsuspension. The nanosuspension system was also physically and chemically stable over a period of 2 years, as indicated by the unchanged particle size and specification tests. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24239080 [article] New approach to pesticide delivery using nanosuspensions : research and applications [texte imprimé] / Chih-Ping Chin, Auteur ; Ho-Shing Wu, Auteur ; Shaw S. Wang, Auteur . - 2011 . - pp. 7637-7643. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 12 (Juin 2011) . - pp. 7637-7643 Mots-clés : Pesticides Résumé : In pharmacology, development of a formulated nanosuspension, a potential drug delivery system for poorly soluble drugs, has been investigated to overcome the bioavailability problems caused by weak solubility, limited chemical stability following administration (i.e., a short half-life), poor bioavailability, and potentially strong side effects requiring drug enrichment at the site of action. For first time use in a pesticide delivery system, a two-step milling process for preparing a nanosuspension in a system of active compound/surfactant/water is described in this paper. First, all the components were mixed at a certain composition to prepare a microsuspension by the general milling process. Then, the microsuspension was taken into a nanomilling process with zirconium oxide beads, having a diameter range of 0.1―0.2 mm, as the milling media to generate the nanosuspension. Therefore, a nanosuspension concentrate was formed. To demonstrate the potential applications of this novel system, it was used to make a formulation with a poorly soluble crystalline insecticide, carbofuran. In a comparative study, two kinds of carbofuran formulations, a microsuspension (commercial) and a nanosuspension, were administered to a diamondback moth (DBM) to test their efficacy and stability as a pesticide. The results indicate that carbofuran has the same efficacy at a lower dose for the nanosuspension compared to the microsuspension. The nanosuspension system was also physically and chemically stable over a period of 2 years, as indicated by the unchanged particle size and specification tests. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24239080

Study on the performance of lambda cyhalothrin microemulsion with biodiesel as an alternative solvent / Chih-Ping Chin in Industrial & engineering chemistry research, Vol. 51 N° 12 (Mars 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 12 (Mars 2012) . - pp. 4710–4718 Titre : Study on the performance of lambda cyhalothrin microemulsion with biodiesel as an alternative solvent Type de document : texte imprimé Auteurs : Chih-Ping Chin, Auteur ; Chi-Wei Lan, Auteur ; Ho-Shing Wu, Auteur Année de publication : 2012 Article en page(s) : pp. 4710–4718 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Microemulsion  Biodiesel  Solvent Résumé : This study investigates a lambda cyhalothrin 2.5% (w/w) microemulsion formulation, with biodiesel as an alternative solvent, as a potential pesticide delivery system for oil-soluble pesticide active ingredients (AIs). This study presents a pseudoternary phase diagram of the investigated system, at room temperature by titration, and the surfactant/cosurfactant mass ratios (S/C), the oil-to-surfactant/cosurfactant mass ratios (O/SC) and the optimum formulation. This study also investigates the continuous structural inversion from water-in-oil to oil-in-water microemulsions after dilution with the water phase. The electrical conductivities of the selected system at constant S/C (5:1) and O/SC (1:1.2) ratios with biodiesel were also studied, and the percolation phenomenon was observed. The study examines the performance and stability of a formulation with biodiesel in comparison to commercial formulations. Residue and phytotoxicity tests were carried out on cabbage plants in a greenhouse. Experimental results indicate that biodiesel has good handling characteristics when it forms a microemulsion. The microemulsion formulation, with biodiesel as a solvent, had an acceptable transparent appearance, broader transparency temperature range, and better performance and stability than the commercial formulation. Using biodiesel in a pesticide formulation had no adverse effects on the AI activity and is comparatively safe for crops and plants. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie201151p [article] Study on the performance of lambda cyhalothrin microemulsion with biodiesel as an alternative solvent [texte imprimé] / Chih-Ping Chin, Auteur ; Chi-Wei Lan, Auteur ; Ho-Shing Wu, Auteur . - 2012 . - pp. 4710–4718. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 12 (Mars 2012) . - pp. 4710–4718 Mots-clés : Microemulsion  Biodiesel  Solvent Résumé : This study investigates a lambda cyhalothrin 2.5% (w/w) microemulsion formulation, with biodiesel as an alternative solvent, as a potential pesticide delivery system for oil-soluble pesticide active ingredients (AIs). This study presents a pseudoternary phase diagram of the investigated system, at room temperature by titration, and the surfactant/cosurfactant mass ratios (S/C), the oil-to-surfactant/cosurfactant mass ratios (O/SC) and the optimum formulation. This study also investigates the continuous structural inversion from water-in-oil to oil-in-water microemulsions after dilution with the water phase. The electrical conductivities of the selected system at constant S/C (5:1) and O/SC (1:1.2) ratios with biodiesel were also studied, and the percolation phenomenon was observed. The study examines the performance and stability of a formulation with biodiesel in comparison to commercial formulations. Residue and phytotoxicity tests were carried out on cabbage plants in a greenhouse. Experimental results indicate that biodiesel has good handling characteristics when it forms a microemulsion. The microemulsion formulation, with biodiesel as a solvent, had an acceptable transparent appearance, broader transparency temperature range, and better performance and stability than the commercial formulation. Using biodiesel in a pesticide formulation had no adverse effects on the AI activity and is comparatively safe for crops and plants. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie201151p