Article : texte imprimé

Catalytic cyclic carbonate synthesis using epoxide and carbon dioxide : combined catalytic effect of both cation and anion of an ionic CrV(O) amido macrocyclic complex

Punnamchandar Ramidi, Auteur ; Shane Z. Sullivan, Auteur ; Yashraj Gartia, Auteur |

Dans Industrial & engineering chemistry research (Vol. 50 N° 13, Juillet 2011)

We have studied an ionic CrV(O) complex of a cyclic amido ligand (1) for cyclic carbonate synthesis using epoxide and carbon dioxide (CO2) as starting materials. Lithium salt of 1 (Li1) showed a high turnover number (TON) of 2950 at 180 °C and 4[...]

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