| Titre : | Conversion of benzylic bromides to benzaldehydes using sodium nitrate as an oxidant (2010) |
| Auteurs : | K. Kulangiappar, Auteur ; M. Anbu Kulandainathan, Auteur ; T. Raju, Auteur |
| Type de document : | Article : texte imprimé |
| Dans : | Industrial & engineering chemistry research (Vol. 49 N° 14, Juillet 2010) |
| Article en page(s) : | pp. 6670–6673 |
| Note générale : | Industrial chemistry |
| Langues : | Anglais |
| Tags : | Sodium nitrate Oxidant |
| Résumé : | A simple and effective approach for the synthesis of benzaldehydes from benzylic bromides is reported using sodium nitrate as an oxidant with 10% sodium hydroxide. Benzyl bromide is oxidized to benzaldehyde in 91% yield with 98% conversion at 120 °C, whereas 82% of benzyl alcohol is obtained at a temperature of 80 °C in 80 min with 20% sodium nitrate solution. |
| ISSN : | 0888-5885 |
| En ligne : | http://pubs.acs.org/doi/abs/10.1021/ie901986g |
