Laboratory studies on the preparation procedures of alumina converted from aluminum citrate / Zhanglong Yu in Industrial & engineering chemistry research, Vol. 49 N° 4 (Fevrier 2010)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 49 N° 4 (Fevrier 2010) . - pp 1832–1836 Titre : Laboratory studies on the preparation procedures of alumina converted from aluminum citrate Type de document : texte imprimé Auteurs : Zhanglong Yu, Auteur ; Lv, Yajing, Auteur ; Yongmei Chen, Auteur Année de publication : 2010 Article en page(s) : pp 1832–1836 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Alumina industry Citric acid. Résumé : It is a promising technology in the alumina industry using citric acid to extract aluminum from clay or kaolin and obtain the solution of aluminum citrate (AlCit). But the prerequisite of the preparation procedure of alumina started from AlCit is that citric acid should be recycled. A process named AlCit−Dawsonite−alumina is proposed in this paper. By using Dawsonite as an intermediate, citrate groups could be separated and reused. The process was verified in laboratory scale: First, Dawsonite was precipitated from AlCit solution with a satisfied purity and conversion rate. Second, Dawsonite was transformed to alumina with low Na content through the two proposed methods. The structure and purity of the intermediate of Dawsonite and products of alumina were characterized by infrared, thermogravimetric−differential thermal analysis, X-ray diffraction, scanning electron microscopy, and inductively coupled plasma. The results show that the synthesized Dawsonite has a great purity and perfect crystallinity; and the Na content of the final alumina product is lower than 0.2%. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie901400r [article] Laboratory studies on the preparation procedures of alumina converted from aluminum citrate [texte imprimé] / Zhanglong Yu, Auteur ; Lv, Yajing, Auteur ; Yongmei Chen, Auteur . - 2010 . - pp 1832–1836. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 4 (Fevrier 2010) . - pp 1832–1836 Mots-clés : Alumina industry Citric acid. Résumé : It is a promising technology in the alumina industry using citric acid to extract aluminum from clay or kaolin and obtain the solution of aluminum citrate (AlCit). But the prerequisite of the preparation procedure of alumina started from AlCit is that citric acid should be recycled. A process named AlCit−Dawsonite−alumina is proposed in this paper. By using Dawsonite as an intermediate, citrate groups could be separated and reused. The process was verified in laboratory scale: First, Dawsonite was precipitated from AlCit solution with a satisfied purity and conversion rate. Second, Dawsonite was transformed to alumina with low Na content through the two proposed methods. The structure and purity of the intermediate of Dawsonite and products of alumina were characterized by infrared, thermogravimetric−differential thermal analysis, X-ray diffraction, scanning electron microscopy, and inductively coupled plasma. The results show that the synthesized Dawsonite has a great purity and perfect crystallinity; and the Na content of the final alumina product is lower than 0.2%. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie901400r

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Preparation of alumina from heated kaolin leached by citric acid with AACH as an intermediate / Zhanglong Yu in Industrial & engineering chemistry research, Vol. 50 N° 14 (Juillet 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 14 (Juillet 2011) . - pp. 8524–8528 Titre : Preparation of alumina from heated kaolin leached by citric acid with AACH as an intermediate Type de document : texte imprimé Auteurs : Zhanglong Yu, Auteur ; Yongmei Chen, Auteur ; Zhixia Shi, Auteur Année de publication : 2011 Article en page(s) : pp. 8524–8528 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Preparation Heated kaolin Résumé : Because the supply of bauxite ores in many countries is becoming deficient, a process of preparing alumina from an alternative resource, namely, kaolin, is proposed in this work. First, kaolin was heated at 600 °C for 2 h before being leached with 1 M citric acid solution, about 75% of the Al in kaolin entered the leachate as aluminum citrate (AlCit) solution. Then, about 50% of the Al(III) in the leachate could be precipitated as ammonium aluminum carbonate hydroxide (AACH) by addition of NH4HCO3 at pH 9.00 ± 0.50. The morphology of AACH characterized by SEM and TEM was spherical particles composed of many nanorods with sizes of about 500 × 25 nm. Finally, mesoporous γ-Al2O3 was obtained by roasting AACH at 700 °C. The Fe and Na contents in the obtained γ-Al2O3 product determined by XRD and ICP-AES were 2 and 0.1 ppm, respectively. The obtained γ-Al2O3 had a morphology similar to that of AACH, and its BET surface area was as high as 235.2 m2/g. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24346893 [article] Preparation of alumina from heated kaolin leached by citric acid with AACH as an intermediate [texte imprimé] / Zhanglong Yu, Auteur ; Yongmei Chen, Auteur ; Zhixia Shi, Auteur . - 2011 . - pp. 8524–8528. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 14 (Juillet 2011) . - pp. 8524–8528 Mots-clés : Preparation Heated kaolin Résumé : Because the supply of bauxite ores in many countries is becoming deficient, a process of preparing alumina from an alternative resource, namely, kaolin, is proposed in this work. First, kaolin was heated at 600 °C for 2 h before being leached with 1 M citric acid solution, about 75% of the Al in kaolin entered the leachate as aluminum citrate (AlCit) solution. Then, about 50% of the Al(III) in the leachate could be precipitated as ammonium aluminum carbonate hydroxide (AACH) by addition of NH4HCO3 at pH 9.00 ± 0.50. The morphology of AACH characterized by SEM and TEM was spherical particles composed of many nanorods with sizes of about 500 × 25 nm. Finally, mesoporous γ-Al2O3 was obtained by roasting AACH at 700 °C. The Fe and Na contents in the obtained γ-Al2O3 product determined by XRD and ICP-AES were 2 and 0.1 ppm, respectively. The obtained γ-Al2O3 had a morphology similar to that of AACH, and its BET surface area was as high as 235.2 m2/g. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24346893

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