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Carbon dioxide capture from flue gases using a cross - flow membrane contactor and the ionic liquid 1 - ethyl - 3 - methylimidazolium ethylsulfate / Jonathan Albo in Industrial & engineering chemistry research, Vol. 49 N° 21 (Novembre 2010) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 49 N° 21 (Novembre 2010) . - pp. 11045-11051 Titre : Carbon dioxide capture from flue gases using a cross - flow membrane contactor and the ionic liquid 1 - ethyl - 3 - methylimidazolium ethylsulfate Type de document : texte imprimé Auteurs : Jonathan Albo, Auteur ; Patricia Luis, Auteur ; Angel Irabien, Auteur Année de publication : 2011 Article en page(s) : pp. 11045-11051 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Ionic  liquid  Crossflow  Carbon  dioxide Résumé : Carbon dioxide (CO2) emissions have to be controlled and reduced in order to avoid environmental risks. Membrane processes in combination with the use of ionic liquids are recently under research and development in order to demonstrate a zero solvent emission process for CO2 capture. In this work, the application of a cross-flow membrane contactor is studied for CO2 absorption when the ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate is used as solvent. A mathematical model considering a parallel flow configuration is applied for a cross-flow system in order to describe the mass transfer rate. At a macroscopic level, Koveralla is calculated considering different mixing models corresponding to plug flow and continuous stirred models and a first order mass transfer rate. A microscopic model based on laminar flow has been applied, obtaining a membrane mass transfer coefficient of km = 3.78 × 10―6 m•s ', which is about five times higher than that obtained in the macroscopic model. The interfacial area, a, allows the comparison of efficiencies between cross-flow and parallel membrane contactor systems in terms of the product (Koveralla). ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23448000 [article] Carbon dioxide capture from flue gases using a cross - flow membrane contactor and the ionic liquid 1 - ethyl - 3 - methylimidazolium ethylsulfate [texte imprimé] / Jonathan Albo, Auteur ; Patricia Luis, Auteur ; Angel Irabien, Auteur . - 2011 . - pp. 11045-11051. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 21 (Novembre 2010) . - pp. 11045-11051 Mots-clés : Ionic  liquid  Crossflow  Carbon  dioxide Résumé : Carbon dioxide (CO2) emissions have to be controlled and reduced in order to avoid environmental risks. Membrane processes in combination with the use of ionic liquids are recently under research and development in order to demonstrate a zero solvent emission process for CO2 capture. In this work, the application of a cross-flow membrane contactor is studied for CO2 absorption when the ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate is used as solvent. A mathematical model considering a parallel flow configuration is applied for a cross-flow system in order to describe the mass transfer rate. At a macroscopic level, Koveralla is calculated considering different mixing models corresponding to plug flow and continuous stirred models and a first order mass transfer rate. A microscopic model based on laminar flow has been applied, obtaining a membrane mass transfer coefficient of km = 3.78 × 10―6 m•s ', which is about five times higher than that obtained in the macroscopic model. The interfacial area, a, allows the comparison of efficiencies between cross-flow and parallel membrane contactor systems in terms of the product (Koveralla). ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23448000

Effect of membrane filtration on ozonation efficiency for removal of atrazine from surface water / Patricia Luis in Industrial & engineering chemistry research, Vol. 50 N° 14 (Juillet 2011) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 50 N° 14 (Juillet 2011) . - pp. 8686-8692 Titre : Effect of membrane filtration on ozonation efficiency for removal of atrazine from surface water Type de document : texte imprimé Auteurs : Patricia Luis, Auteur ; Mohd Saquib, Auteur ; Chris Vinckier, Auteur Année de publication : 2011 Article en page(s) : pp. 8686-8692 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Membrane  separation  Surface  water  Ozonization  Membrane  filtration Résumé : The kinetics of the decay rate of atrazine from surface water by ozonation was studied at pH 3, 7, and 9 without and with pretreatment with several pressure-driven membrane filtration methods: ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO), in order to determine the influence of the feedwater quality on the chemical oxidation of atrazine. First, the atrazine decay rate was determined in surface water (without pretreatment with membranes) in the presence of natural organic matter (NOM). An increase in the atrazine decay rate is observed at pH 3 and 7 in surface water, which can be attributed to the presence of NOM since it acts as OH radicals promoter. However, at pH = 9, the NOM effect vanishes since at this high pH, the advanced oxidation process (AOP) effect becomes far dominant. The efficiency of combining membrane filtration techniques with a subsequent ozonation step for removing atrazine from surface water mainly depends on the pH and the molecular weight fraction of the NOM. Under acidic conditions only UF enhances the atrazine decay rate since this technique does not retain the low molecular weight fraction of the NOM, which acts as OH radical promoter, while removing the high molecular weight fraction of the NOM which acts as a radical scavenger. At pH = 7, the presence of carbonate/bicarbonate ions as OH radical scavengers starts to prevail over the NOM effect. Because RO is the most efficient technique to decrease the carbonate/bicarbonate content, RO enhances the atrazine decay by more than 50%. At pH = 9, the AOP effect becomes by far dominant and annuls the NOM and carbonate/ bicarbonate effect. The efficiency of membrane filtration techniques becomes doubtful in view of their marginal effe DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24346907 [article] Effect of membrane filtration on ozonation efficiency for removal of atrazine from surface water [texte imprimé] / Patricia Luis, Auteur ; Mohd Saquib, Auteur ; Chris Vinckier, Auteur . - 2011 . - pp. 8686-8692. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 14 (Juillet 2011) . - pp. 8686-8692 Mots-clés : Membrane  separation  Surface  water  Ozonization  Membrane  filtration Résumé : The kinetics of the decay rate of atrazine from surface water by ozonation was studied at pH 3, 7, and 9 without and with pretreatment with several pressure-driven membrane filtration methods: ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO), in order to determine the influence of the feedwater quality on the chemical oxidation of atrazine. First, the atrazine decay rate was determined in surface water (without pretreatment with membranes) in the presence of natural organic matter (NOM). An increase in the atrazine decay rate is observed at pH 3 and 7 in surface water, which can be attributed to the presence of NOM since it acts as OH radicals promoter. However, at pH = 9, the NOM effect vanishes since at this high pH, the advanced oxidation process (AOP) effect becomes far dominant. The efficiency of combining membrane filtration techniques with a subsequent ozonation step for removing atrazine from surface water mainly depends on the pH and the molecular weight fraction of the NOM. Under acidic conditions only UF enhances the atrazine decay rate since this technique does not retain the low molecular weight fraction of the NOM, which acts as OH radical promoter, while removing the high molecular weight fraction of the NOM which acts as a radical scavenger. At pH = 7, the presence of carbonate/bicarbonate ions as OH radical scavengers starts to prevail over the NOM effect. Because RO is the most efficient technique to decrease the carbonate/bicarbonate content, RO enhances the atrazine decay by more than 50%. At pH = 9, the AOP effect becomes by far dominant and annuls the NOM and carbonate/ bicarbonate effect. The efficiency of membrane filtration techniques becomes doubtful in view of their marginal effe DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24346907