| Titre : | A simple and environmentally benign method for sulfoxidation of sulfides with hydrogen peroxide (2010) |
| Auteurs : | Liu Fenglan, Auteur ; Fu Zaihui, Auteur ; Liu Yachun, Auteur |
| Type de document : | Article : texte imprimé |
| Dans : | Industrial & engineering chemistry research (Vol. 49 N° 5, Mars 2010) |
| Article en page(s) : | pp. 2533–2536 |
| Note générale : | Industrial Chemistry |
| Langues : | Anglais |
| Tags : | Hydrogen Peroxide ; sulfides |
| Résumé : | The development of a simple, efficient, and environmentally benign method for the sulfoxidation of sulfides with aqueous hydrogen peroxide is of importance for the large-scale industrial production of sulfoxides. This article first discloses that various aryl and alkyl sulfides, without help of any catalyst and extra solvent, can be directly oxidized by 30% aqueous hydrogen peroxide to the corresponding sulfoxides with good to excellent yield at 60 °C. Furthermore, the present method has outstanding advantages, with regard to reaction rate and sulfoxide yield, compared with a series of organic solvents-mediated reactions |
| Note de contenu : | Bibliogr. |
| ISSN : | 0888-5885 |
| En ligne : | http://pubs.acs.org/doi/abs/10.1021/ie9017572 |
