Effect of microwave treatment on structural changes and gasification reactivity of petroleum coke / Xin Liu in Industrial & engineering chemistry research, Vol. 50 N° 15 (Août 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 15 (Août 2011) . - pp. 9063-9068 Titre : Effect of microwave treatment on structural changes and gasification reactivity of petroleum coke Type de document : texte imprimé Auteurs : Xin Liu, Auteur ; Zhi-jie Zhou, Auteur ; Bao-shen Zhang, Auteur Année de publication : 2011 Article en page(s) : pp. 9063-9068 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Petroleum Chemical reactivity Gasification Microwave Résumé : The gasification reactivity of petroleum coke, which was treated by microwave at different times, powers, and temperatures, was investigated by using thermogravimetric analysis (TGA) at 1473 K at atmospheric pressure. The results showed that the gasification rate of petroleum coke increased with the increase of conversion and then decreased after reaching its maximum; the conversion corresponding to the maximal gasification rate is about x=0.1. The gasification rate of petroleum coke increased with the increase of microwave irradiation time and irradiation power, but as the irradiation temperature increased, the gasification rate of petroleum coke first increased and then decreased. Petroleum coke before and after microwave treatment was analyzed by X-ray diffraction (XRD), infrared absorption spectroscopy (IR), and the accelerated surface area and porosimetry system (ASAP). The results showed that the crystalline structure of petroleum coke becomes amorphous and the BET surface area and pore volume become larger with increase of microwave irradiation time and irradiation power. As the irradiation temperature increased, the crystalline ordering degree of petroleum coke became weakened and then strengthened and the BET surface area and pore volume increased and then decreased, which agrees with the change in the petroleum coke gasification reaction rate. Results show that microwave treatment is an effective way to change the structure of petroleum coke and promote its gasification reactivity. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24395853 [article] Effect of microwave treatment on structural changes and gasification reactivity of petroleum coke [texte imprimé] / Xin Liu, Auteur ; Zhi-jie Zhou, Auteur ; Bao-shen Zhang, Auteur . - 2011 . - pp. 9063-9068. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 15 (Août 2011) . - pp. 9063-9068 Mots-clés : Petroleum Chemical reactivity Gasification Microwave Résumé : The gasification reactivity of petroleum coke, which was treated by microwave at different times, powers, and temperatures, was investigated by using thermogravimetric analysis (TGA) at 1473 K at atmospheric pressure. The results showed that the gasification rate of petroleum coke increased with the increase of conversion and then decreased after reaching its maximum; the conversion corresponding to the maximal gasification rate is about x=0.1. The gasification rate of petroleum coke increased with the increase of microwave irradiation time and irradiation power, but as the irradiation temperature increased, the gasification rate of petroleum coke first increased and then decreased. Petroleum coke before and after microwave treatment was analyzed by X-ray diffraction (XRD), infrared absorption spectroscopy (IR), and the accelerated surface area and porosimetry system (ASAP). The results showed that the crystalline structure of petroleum coke becomes amorphous and the BET surface area and pore volume become larger with increase of microwave irradiation time and irradiation power. As the irradiation temperature increased, the crystalline ordering degree of petroleum coke became weakened and then strengthened and the BET surface area and pore volume increased and then decreased, which agrees with the change in the petroleum coke gasification reaction rate. Results show that microwave treatment is an effective way to change the structure of petroleum coke and promote its gasification reactivity. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24395853

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