Biogenic silver nanoparticles by cacumen platycladi extract / Jiale Huang in Industrial & engineering chemistry research, Vol. 50 N° 15 (Août 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 15 (Août 2011) . - pp. 9095-9106 Titre : Biogenic silver nanoparticles by cacumen platycladi extract : synthesis, formation mechanism, and antibacterial activity Type de document : texte imprimé Auteurs : Jiale Huang, Auteur ; Guowu Zhan, Auteur ; Bingyun Zheng, Auteur Année de publication : 2011 Article en page(s) : pp. 9095-9106 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Formation mechanism Extract Nanoparticle Biogenic factor Résumé : Biosynthesis of Ag nanoparticles (AgNPs) by Cacumen Platycladi extract was investigated. The AgNPs were characterized by ultraviolet-visible absorption spectroscopy (UV-vis), transmission electron microscopy (TEM), selected-area electron diffraction (SAED), and X-ray diffraction (XRD). The results showed that increasing the initial AgNO3 concentration at 30 or 60 °C increased the mean size and widened the size distribution of the AgNPs leading to red shift and broadening of the Surface Plasmon Resonance absorption. The conversion of silver ions was determined by atomic absorption spectroscopy (AAS) and to discuss the bioreductive mechanism, the reducing sugar, flavonoid, saccharide, protein contents in the extract, and the antioxidant activity were measured using 3,5-dinitrosalicylic acid colorimetric; Coomassie brilliant blue; phenol-sulfuric acid; rutin-based spectrophotometry method; and 2,2-diphenyl-1-picrylhydrazyl (DPPH) free radical-scavenging assay methods. The results showed that the reducing sugars and flavonoids were mainly responsible for the bioreduction of the silver ions and their reductive capability promoted at 90 °C, leading to the formation of AgNPs (18.4 ± 4.6 nm) with narrow size distribution. Finally, the antibacterial activity of the AgNPs against E. coli and S. aureus was assessed to determine their potential applications in silver-loaded antibacterial materials. This work provides useful technical parameters for industrialization ofthe biosynthetic technique and further antibacterial application of the AgNPs. Furthermore, the elucidation of bioreductive mechanism of silver ions by measuring the change of the biomolecular concentrations in plant extract exemplifies understanding the formation mechanism of such biogenic AgNPs. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24395857 [article] Biogenic silver nanoparticles by cacumen platycladi extract : synthesis, formation mechanism, and antibacterial activity [texte imprimé] / Jiale Huang, Auteur ; Guowu Zhan, Auteur ; Bingyun Zheng, Auteur . - 2011 . - pp. 9095-9106. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 15 (Août 2011) . - pp. 9095-9106 Mots-clés : Formation mechanism Extract Nanoparticle Biogenic factor Résumé : Biosynthesis of Ag nanoparticles (AgNPs) by Cacumen Platycladi extract was investigated. The AgNPs were characterized by ultraviolet-visible absorption spectroscopy (UV-vis), transmission electron microscopy (TEM), selected-area electron diffraction (SAED), and X-ray diffraction (XRD). The results showed that increasing the initial AgNO3 concentration at 30 or 60 °C increased the mean size and widened the size distribution of the AgNPs leading to red shift and broadening of the Surface Plasmon Resonance absorption. The conversion of silver ions was determined by atomic absorption spectroscopy (AAS) and to discuss the bioreductive mechanism, the reducing sugar, flavonoid, saccharide, protein contents in the extract, and the antioxidant activity were measured using 3,5-dinitrosalicylic acid colorimetric; Coomassie brilliant blue; phenol-sulfuric acid; rutin-based spectrophotometry method; and 2,2-diphenyl-1-picrylhydrazyl (DPPH) free radical-scavenging assay methods. The results showed that the reducing sugars and flavonoids were mainly responsible for the bioreduction of the silver ions and their reductive capability promoted at 90 °C, leading to the formation of AgNPs (18.4 ± 4.6 nm) with narrow size distribution. Finally, the antibacterial activity of the AgNPs against E. coli and S. aureus was assessed to determine their potential applications in silver-loaded antibacterial materials. This work provides useful technical parameters for industrialization ofthe biosynthetic technique and further antibacterial application of the AgNPs. Furthermore, the elucidation of bioreductive mechanism of silver ions by measuring the change of the biomolecular concentrations in plant extract exemplifies understanding the formation mechanism of such biogenic AgNPs. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24395857

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