Improving the adsorption of heavy metals from water using commercial carbons modified with egg shell wastes / Alejandro Guijarro-Aldaco in Industrial & engineering chemistry research, Vol. 50 N° 15 (Août 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 15 (Août 2011) . - pp. 9354-9362 Titre : Improving the adsorption of heavy metals from water using commercial carbons modified with egg shell wastes Type de document : texte imprimé Auteurs : Alejandro Guijarro-Aldaco, Auteur ; Virginia Hernandez-Montoya, Auteur ; Adrian Bonilla-Petriciolet, Auteur Année de publication : 2011 Article en page(s) : pp. 9354-9362 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Heavy metal Adsorption Résumé : We introduce the application of hen egg shell waste to improve the adsorption capacities of heavy-metal ions using commercial carbons via the modification of their surface chemistry. Specifically, a calcium solution extracted from egg shell waste has been used as a low-cost activation agent to improve the adsorption properties of three commercial carbons. An orthogonal array of the Taguchi method has been applied to identify the optimal conditions for the adsorbent modification process using the Zn2+ batch adsorption, at 30 °C and pH 5, as the response variable. Our results show that maximum adsorption capacities of Cd2+, Ni2+, and Zn2+ ions, at 30 °C and pH 5, may increase up to 15 times, with respect to the results obtained using the commercial adsorbent without modification. The improvement of adsorbent performance may be related to the formation of calcium phosphate on the carbon surface. Finally, adsorption studies in binary metal solutions were performed to identify the competitive effects in multicomponent adsorption, using calcium-modified carbons. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24395880 [article] Improving the adsorption of heavy metals from water using commercial carbons modified with egg shell wastes [texte imprimé] / Alejandro Guijarro-Aldaco, Auteur ; Virginia Hernandez-Montoya, Auteur ; Adrian Bonilla-Petriciolet, Auteur . - 2011 . - pp. 9354-9362. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 15 (Août 2011) . - pp. 9354-9362 Mots-clés : Heavy metal Adsorption Résumé : We introduce the application of hen egg shell waste to improve the adsorption capacities of heavy-metal ions using commercial carbons via the modification of their surface chemistry. Specifically, a calcium solution extracted from egg shell waste has been used as a low-cost activation agent to improve the adsorption properties of three commercial carbons. An orthogonal array of the Taguchi method has been applied to identify the optimal conditions for the adsorbent modification process using the Zn2+ batch adsorption, at 30 °C and pH 5, as the response variable. Our results show that maximum adsorption capacities of Cd2+, Ni2+, and Zn2+ ions, at 30 °C and pH 5, may increase up to 15 times, with respect to the results obtained using the commercial adsorbent without modification. The improvement of adsorbent performance may be related to the formation of calcium phosphate on the carbon surface. Finally, adsorption studies in binary metal solutions were performed to identify the competitive effects in multicomponent adsorption, using calcium-modified carbons. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24395880

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