Selective separation of Cu(II) from aqueous solution with a novel Cu(II) surface magnetic ion-imprinted polymer / Youcai Zhan in Industrial & engineering chemistry research, Vol. 50 N° 10 (Mai 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 10 (Mai 2011) . - pp. 6355-6361 Titre : Selective separation of Cu(II) from aqueous solution with a novel Cu(II) surface magnetic ion-imprinted polymer Type de document : texte imprimé Auteurs : Youcai Zhan, Auteur ; Xubiao Luo, Auteur ; Shanshan Nie, Auteur Année de publication : 2011 Article en page(s) : pp. 6355-6361 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Aqueous solution Résumé : A novel Cu(II) magnetic ion-imprinted polymer (MIIP) was prepared via the sol-gel method. The Cu(II)-MIIP exhibited good magnetic property and thermal stability. The binding characteristics of Cu(II)-MIIP were studied by adopting both static and dynamic adsorption experiments. The maximum adsorptions calculated from the Langmuir isotherm are 58.20 and 23.10 mg/g for Cu(II)-MIIP and magnetic nonimprinted polymer (MNIP), respectively. The kinetics studies showed that the adsorption process obeyed a pseudo-second-order kinetic model. The selectivity coefficients of the Cu(II)-MIIP for Cu(II) in the presence of Zn(II) and Ni(II) are 49.44 and 50.38, respectively. The relative selectivity coefficients of cu(II)-MIIP for Cu(II)/Zn(II) and Cu(II)/Ni(II) are 12.36 and 8.73, respectively. Moreover, Cu(II)-MIIP could be used five times without obvious deterioration in their adsorption capacities. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24158931 [article] Selective separation of Cu(II) from aqueous solution with a novel Cu(II) surface magnetic ion-imprinted polymer [texte imprimé] / Youcai Zhan, Auteur ; Xubiao Luo, Auteur ; Shanshan Nie, Auteur . - 2011 . - pp. 6355-6361. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 10 (Mai 2011) . - pp. 6355-6361 Mots-clés : Aqueous solution Résumé : A novel Cu(II) magnetic ion-imprinted polymer (MIIP) was prepared via the sol-gel method. The Cu(II)-MIIP exhibited good magnetic property and thermal stability. The binding characteristics of Cu(II)-MIIP were studied by adopting both static and dynamic adsorption experiments. The maximum adsorptions calculated from the Langmuir isotherm are 58.20 and 23.10 mg/g for Cu(II)-MIIP and magnetic nonimprinted polymer (MNIP), respectively. The kinetics studies showed that the adsorption process obeyed a pseudo-second-order kinetic model. The selectivity coefficients of the Cu(II)-MIIP for Cu(II) in the presence of Zn(II) and Ni(II) are 49.44 and 50.38, respectively. The relative selectivity coefficients of cu(II)-MIIP for Cu(II)/Zn(II) and Cu(II)/Ni(II) are 12.36 and 8.73, respectively. Moreover, Cu(II)-MIIP could be used five times without obvious deterioration in their adsorption capacities. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24158931

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