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Direct oxidation of methane to a methanol derivative using molecular oxygen / Jiongliang Yuan in Industrial & engineering chemistry research, Vol. 50 N° 10 (Mai 2011) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 50 N° 10 (Mai 2011) . - pp. 6513-6516 Titre : Direct oxidation of methane to a methanol derivative using molecular oxygen Type de document : texte imprimé Auteurs : Jiongliang Yuan, Auteur ; Lanlan Wang, Auteur ; Yan Wang, Auteur Année de publication : 2011 Article en page(s) : pp. 6513-6516 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Oxidation Résumé : A direct selective oxidation of methane to a methanol derivative with the catalysis of palladium acetate/ benzoquinone/molybdovanado-phosphoric acid using molecular oxygen in trifluoroacetic acid has been suggested. Methyl trifluoroacetate is the only liquid product, and its highest yield could be obtained at 80-100 °C. The addition of perfluorooctane could improve the yield of methyl trifluoroacetate significantly. The reaction product can be easily separated from the reaction system, using the difference of boiling points. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24158950 [article] Direct oxidation of methane to a methanol derivative using molecular oxygen [texte imprimé] / Jiongliang Yuan, Auteur ; Lanlan Wang, Auteur ; Yan Wang, Auteur . - 2011 . - pp. 6513-6516. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 10 (Mai 2011) . - pp. 6513-6516 Mots-clés : Oxidation Résumé : A direct selective oxidation of methane to a methanol derivative with the catalysis of palladium acetate/ benzoquinone/molybdovanado-phosphoric acid using molecular oxygen in trifluoroacetic acid has been suggested. Methyl trifluoroacetate is the only liquid product, and its highest yield could be obtained at 80-100 °C. The addition of perfluorooctane could improve the yield of methyl trifluoroacetate significantly. The reaction product can be easily separated from the reaction system, using the difference of boiling points. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24158950