[article]
| Titre : |
Direct oxidation of methane to a methanol derivative using molecular oxygen |
| Type de document : |
texte imprimé |
| Auteurs : |
Jiongliang Yuan, Auteur ; Lanlan Wang, Auteur ; Yan Wang, Auteur |
| Année de publication : |
2011 |
| Article en page(s) : |
pp. 6513-6516 |
| Note générale : |
Chimie industrielle |
| Langues : |
Anglais (eng) |
| Mots-clés : |
Oxidation |
| Résumé : |
A direct selective oxidation of methane to a methanol derivative with the catalysis of palladium acetate/ benzoquinone/molybdovanado-phosphoric acid using molecular oxygen in trifluoroacetic acid has been suggested. Methyl trifluoroacetate is the only liquid product, and its highest yield could be obtained at 80-100 °C. The addition of perfluorooctane could improve the yield of methyl trifluoroacetate significantly. The reaction product can be easily separated from the reaction system, using the difference of boiling points. |
| DEWEY : |
660 |
| ISSN : |
0888-5885 |
| En ligne : |
http://cat.inist.fr/?aModele=afficheN&cpsidt=24158950 |
in Industrial & engineering chemistry research > Vol. 50 N° 10 (Mai 2011) . - pp. 6513-6516
[article] Direct oxidation of methane to a methanol derivative using molecular oxygen [texte imprimé] / Jiongliang Yuan, Auteur ; Lanlan Wang, Auteur ; Yan Wang, Auteur . - 2011 . - pp. 6513-6516. Chimie industrielle Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 50 N° 10 (Mai 2011) . - pp. 6513-6516
| Mots-clés : |
Oxidation |
| Résumé : |
A direct selective oxidation of methane to a methanol derivative with the catalysis of palladium acetate/ benzoquinone/molybdovanado-phosphoric acid using molecular oxygen in trifluoroacetic acid has been suggested. Methyl trifluoroacetate is the only liquid product, and its highest yield could be obtained at 80-100 °C. The addition of perfluorooctane could improve the yield of methyl trifluoroacetate significantly. The reaction product can be easily separated from the reaction system, using the difference of boiling points. |
| DEWEY : |
660 |
| ISSN : |
0888-5885 |
| En ligne : |
http://cat.inist.fr/?aModele=afficheN&cpsidt=24158950 |
|
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