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Improved efficiency of dye-sensitized solar cells using a vertically aligned carbon nanotube counter electrode / Robert A. Sayer in Transactions of the ASME. Journal of solar energy engineering, Vol. 132 N° 2 (Mai 2010) 

Public ISBD [article]  in Transactions of the ASME. Journal of solar energy engineering > Vol. 132 N° 2 (Mai 2010) . - pp. [021007/1-4] Titre : Improved efficiency of dye-sensitized solar cells using a vertically aligned carbon nanotube counter electrode Type de document : texte imprimé Auteurs : Robert A. Sayer, Auteur ; Stephen L. Hodson, Auteur ; Timothy S. Fisher, Auteur Année de publication : 2011 Article en page(s) : pp. [021007/1-4] Note générale : Energie Solaire Langues : Anglais (eng) Mots-clés : Carbon  nanotubes  Electrochemical  electrodes  Plasma  CVD  Solar  cells Index. décimale : 621.47 Résumé : Dye-sensitized solar cells (DSSCs) offer many advantages in comparison to their Si-based counterparts, including lower cost of raw materials, faster manufacturing time, and the ability to be integrated with flexible substrates. Although many advances have been made in DSSC fabrication over recent years, their efficiency remains lower than commercially available Si photovoltaic cells. Here we report improved efficiency of TiO2/anthocyanin dye solar cell using vertically aligned arrays of carbon nanotubes (CNTs) as a counter electrode. Dense vertically oriented CNT arrays are grown directly on the counter electrode using microwave plasma chemical vapor deposition and a trilayer (Ti/Al/Fe) catalyst. The resulting arrays are 30 µm in height and have a number density of approximately 5×108/mm2. By directly growing the CNTs on the counter electrode substrate, electrical interface conductance is enhanced. The performance of both as-grown and N-doped (using a nitrogen plasma) CNT arrays is reported. The fabricated DSSCs are tested under AM1.5 light. Increased short-circuit current is observed in comparison to graphite and Pt counter electrodes. We attribute this improvement to the large surface area created by the 3D structure of the arrays in comparison to the planar geometry of the graphite and Pt electrodes, as well as the excellent electrical properties of the CNTs. DEWEY : 621.47 ISSN : 0199-6231 En ligne : http://asmedl.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JSEEDO00013200 [...] [article] Improved efficiency of dye-sensitized solar cells using a vertically aligned carbon nanotube counter electrode [texte imprimé] / Robert A. Sayer, Auteur ; Stephen L. Hodson, Auteur ; Timothy S. Fisher, Auteur . - 2011 . - pp. [021007/1-4]. Energie Solaire Langues : Anglais (eng) in Transactions of the ASME. Journal of solar energy engineering > Vol. 132 N° 2 (Mai 2010) . - pp. [021007/1-4] Mots-clés : Carbon  nanotubes  Electrochemical  electrodes  Plasma  CVD  Solar  cells Index. décimale : 621.47 Résumé : Dye-sensitized solar cells (DSSCs) offer many advantages in comparison to their Si-based counterparts, including lower cost of raw materials, faster manufacturing time, and the ability to be integrated with flexible substrates. Although many advances have been made in DSSC fabrication over recent years, their efficiency remains lower than commercially available Si photovoltaic cells. Here we report improved efficiency of TiO2/anthocyanin dye solar cell using vertically aligned arrays of carbon nanotubes (CNTs) as a counter electrode. Dense vertically oriented CNT arrays are grown directly on the counter electrode using microwave plasma chemical vapor deposition and a trilayer (Ti/Al/Fe) catalyst. The resulting arrays are 30 µm in height and have a number density of approximately 5×108/mm2. By directly growing the CNTs on the counter electrode substrate, electrical interface conductance is enhanced. The performance of both as-grown and N-doped (using a nitrogen plasma) CNT arrays is reported. The fabricated DSSCs are tested under AM1.5 light. Increased short-circuit current is observed in comparison to graphite and Pt counter electrodes. We attribute this improvement to the large surface area created by the 3D structure of the arrays in comparison to the planar geometry of the graphite and Pt electrodes, as well as the excellent electrical properties of the CNTs. DEWEY : 621.47 ISSN : 0199-6231 En ligne : http://asmedl.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JSEEDO00013200 [...]