Effective light harvesting of tandem polymer solar cell / Yi-Chun Chen in Transactions of the ASME. Journal of solar energy engineering, Vol. 132 N° 2 (Mai 2010)  

Public ISBD [article]  inTransactions of the ASME. Journal of solar energy engineering > Vol. 132 N° 2 (Mai 2010) . - pp. [021103/1-6] Titre : Effective light harvesting of tandem polymer solar cell Type de document : texte imprimé Auteurs : Yi-Chun Chen, Auteur ; Chao-Ying Yu, Auteur ; Chih-Ping Chen, Auteur Année de publication : 2011 Article en page(s) : pp. [021103/1-6] Note générale : Energie Solaire Langues : Anglais (eng) Mots-clés : Conducting polymer Solar cell Tandem Index. décimale : 621.47 Résumé : A novel soluble conjugated polymers, P2, with coplanar thiophene-phenylene-thiophene unit is designed and synthesized as suitable active material used in tandem cells to compensate the poly(3-hexylthiophene) (P3HT)/[6,6]-phenyl-C71 butyric acid methyl ester (PC71BM) bulk-heterojunction cell in this paper. P2 polymer bears advantages in both low optical bandgap (1.7 eV) and high hole mobility properties (3.4×10−3 cm2/V-s from field-effect transistor measurement). Furthermore, the electrochemical studies of P2 indicate desirable highest occupied molecular orbital/lowest unoccupied molecular orbital (HOMO/LUMO) band structure that enables a high open circuit voltage when pairing with PCBM acceptor. The best power conversion efficiency of this polymer solar cell thus far based on P2/PC71BM system with a weight ratio of 1:3 reached 4.4% with a short circuit current density (Jsc) of 10.2 mA/cm2, an open circuit voltage (Voc) of 0.81 V, and a fill factor (FF) of 0.53 under air mass (AM) 1.5 G (100 mW/cm2). The preliminary data of the tandem cell with indium tin oxide (ITO) glass/PEDOT:PSS/P2:PC71BM/TiOx/PEDOT:PSS/P3HT:PC71BM/TiOx/Al configuration has reached Jsc of 6.2 mA/cm2, Voc of 1.33 V, FF of 0.56 and an overall efficiency of 4.6% under AM 1.5 G (100 mW/cm2). DEWEY : 621.47 ISSN : 0199-6231 En ligne : http://asmedl.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JSEEDO00013200 [...] [article] Effective light harvesting of tandem polymer solar cell [texte imprimé] / Yi-Chun Chen, Auteur ; Chao-Ying Yu, Auteur ; Chih-Ping Chen, Auteur . - 2011 . - pp. [021103/1-6]. Energie Solaire Langues : Anglais (eng) in Transactions of the ASME. Journal of solar energy engineering > Vol. 132 N° 2 (Mai 2010) . - pp. [021103/1-6] Mots-clés : Conducting polymer Solar cell Tandem Index. décimale : 621.47 Résumé : A novel soluble conjugated polymers, P2, with coplanar thiophene-phenylene-thiophene unit is designed and synthesized as suitable active material used in tandem cells to compensate the poly(3-hexylthiophene) (P3HT)/[6,6]-phenyl-C71 butyric acid methyl ester (PC71BM) bulk-heterojunction cell in this paper. P2 polymer bears advantages in both low optical bandgap (1.7 eV) and high hole mobility properties (3.4×10−3 cm2/V-s from field-effect transistor measurement). Furthermore, the electrochemical studies of P2 indicate desirable highest occupied molecular orbital/lowest unoccupied molecular orbital (HOMO/LUMO) band structure that enables a high open circuit voltage when pairing with PCBM acceptor. The best power conversion efficiency of this polymer solar cell thus far based on P2/PC71BM system with a weight ratio of 1:3 reached 4.4% with a short circuit current density (Jsc) of 10.2 mA/cm2, an open circuit voltage (Voc) of 0.81 V, and a fill factor (FF) of 0.53 under air mass (AM) 1.5 G (100 mW/cm2). The preliminary data of the tandem cell with indium tin oxide (ITO) glass/PEDOT:PSS/P2:PC71BM/TiOx/PEDOT:PSS/P3HT:PC71BM/TiOx/Al configuration has reached Jsc of 6.2 mA/cm2, Voc of 1.33 V, FF of 0.56 and an overall efficiency of 4.6% under AM 1.5 G (100 mW/cm2). DEWEY : 621.47 ISSN : 0199-6231 En ligne : http://asmedl.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JSEEDO00013200 [...]

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