| Titre : | An electron-beam irradiation/catalytic oxidation system for purification of aromatic hydrocarbons/air mixture under practical gas-flow condition (2010) |
| Auteurs : | Teruyuki Hakoda, Auteur ; Akihiko Shimada, Auteur ; Atsushi Kimura, Auteur |
| Type de document : | Article : texte imprimé |
| Dans : | Industrial & engineering chemistry research (Vol. 49 N° 12, Juin 2010) |
| Article en page(s) : | pp. 5517–5522 |
| Note générale : | Chemical engineering |
| Langues : | Anglais |
| Tags : | Electron-beam (EB) irradiation/catalytic oxidation system Volatile organic compound |
| Résumé : | An electron-beam (EB) irradiation/catalytic oxidation system was developed for the purification of a volatile organic compound (VOC) gas stream under a practical gas flow condition. This system consists of a compact-sized electron accelerator and an ozone decomposition catalyst, which is MnO2. The removal of toluene and/or xylene and their mineralization were examined with and without catalytic oxidation for a gas stream at a flow rate of 500 Nm3 h−1. A combined catalyst bed enhanced the removal of VOCs and the mineralization of VOC and its irradiation organic byproducts. For example, for an initial concentration of 5 ppmv, the removal ratio of toluene and xylene increased from 60% to 91% and from 81% to 91%, respectively, at a dose of 4.4 kGy. The mineralization ratio increased from 42% to 100% by the catalytic treatment at doses higher than 9.3 kGy. Furthermore, the yield of CO2 to COx increased from 52−60% to 83−89% by the catalytic treatment. |
| En ligne : | http://pubs.acs.org/doi/abs/10.1021/ie100278k |
