| Titre : | Intrinsic kinetics of catalytic hydrogenation of cardanol (2010) |
| Auteurs : | Zhi-Bo Mao, Auteur ; Ting-Liang Luo, Auteur ; Hong-Tao Cheng, Auteur |
| Type de document : | Article : texte imprimé |
| Dans : | Industrial & engineering chemistry research (Vol. 48 N° 22, Novembre 2009) |
| Article en page(s) : | pp. 9910–9914 |
| Note générale : | Chemical engineering |
| Langues : | Anglais |
| Tags : | Cardanol Catalytic hydrogenation Raney nickel catalyst |
| Résumé : | The experiment of catalytic hydrogenation of cardanol was performed on a Raney nickel catalyst for the purpose of eliminating the effects of internal and external diffusion. The kinetics data have been collected experimentally over ranges of 2.5−4 MPa and 373.15−393.15 K, respectively. Then, the intrinsic kinetics of the catalytic hydrogenation reaction of cardanol was studied. It was proven that the catalytic hydrogenation of cardanol is a second-order irreversible series-parallel reaction under the experimental conditions. The kinetic parameters (Ea, K0) and kinetic equation were obtained through fitting, and the kinetic model was proven through testing to be reliable. |
| En ligne : | http://pubs.acs.org/doi/abs/10.1021/ie900655a |
