Composition analysis of CO2−NH3−H2O system based on raman spectra / Qing Zhao in Industrial & engineering chemistry research, Vol. 50 N° 9 (Mai 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 9 (Mai 2011) . - pp. 5316–5325 Titre : Composition analysis of CO2−NH3−H2O system based on raman spectra Type de document : texte imprimé Auteurs : Qing Zhao, Auteur ; Shujuan Wang, Auteur ; Feng Qin, Auteur Année de publication : 2011 Article en page(s) : pp. 5316–5325 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Raman spectroscopy Résumé : We used Raman spectroscopy to systematically and comprehensively measure the concentrations of the main ion components (NH2COO−, HCO3−, and CO32−) in the CO2−NH3−H2O system for an initial total ammonia concentration [A] = 0.69, 0.88, 1.09, 1.34, 1.60, and 2.10 mol·L−1 and CO2 loading [C]/[A] = 0.18, 0.35, 0.43, 0.50, and 0.67, respectively. The experimental data were processed using two existing theoretical methods, and the analysis on results allowed us to propose a number of improvements based on these theoretical methods. Experimental results show that upon increasing [C]/[A], the ratios of [NH2COO−] and [CO32−] to total carbon decrease linearly, whereas the ratio of [HCO3−] to total carbon increases linearly. The reaction process can be divided into three steps. Considering the impacts of experiment errors, [A] has little effect on the relative composition of the system in the range we studied. Results calculated with a revised theoretical method are in better agreement with the experimental data. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie1010178 [article] Composition analysis of CO2−NH3−H2O system based on raman spectra [texte imprimé] / Qing Zhao, Auteur ; Shujuan Wang, Auteur ; Feng Qin, Auteur . - 2011 . - pp. 5316–5325. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 9 (Mai 2011) . - pp. 5316–5325 Mots-clés : Raman spectroscopy Résumé : We used Raman spectroscopy to systematically and comprehensively measure the concentrations of the main ion components (NH2COO−, HCO3−, and CO32−) in the CO2−NH3−H2O system for an initial total ammonia concentration [A] = 0.69, 0.88, 1.09, 1.34, 1.60, and 2.10 mol·L−1 and CO2 loading [C]/[A] = 0.18, 0.35, 0.43, 0.50, and 0.67, respectively. The experimental data were processed using two existing theoretical methods, and the analysis on results allowed us to propose a number of improvements based on these theoretical methods. Experimental results show that upon increasing [C]/[A], the ratios of [NH2COO−] and [CO32−] to total carbon decrease linearly, whereas the ratio of [HCO3−] to total carbon increases linearly. The reaction process can be divided into three steps. Considering the impacts of experiment errors, [A] has little effect on the relative composition of the system in the range we studied. Results calculated with a revised theoretical method are in better agreement with the experimental data. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie1010178

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