[article]
Titre : |
Water-dispersed conductive polypyrroles doped with lignosulfonate and the weak temperature dependence of electrical conductivity |
Type de document : |
texte imprimé |
Auteurs : |
Chao Yang, Auteur ; Peng Liu, Auteur |
Année de publication : |
2010 |
Article en page(s) : |
pp. 9498–9503 |
Note générale : |
Chemical engineering |
Langues : |
Anglais (eng) |
Mots-clés : |
Water-dispersed conductive polypyrroles Chemical oxidative polymerization Lignosulfonate |
Résumé : |
The water-dispersed conductive polypyrroles (PPys) were prepared via the chemical oxidative polymerization with lignosulfonate (LGS), an inexpensive byproduct from pulp processing industries, as a dopant and template for tuning the properties of polypyrrole nanoparticles. The lignosulfonate doped polypyrrole (PPy/LGS) nanoparticles were characterized with Fourier transform infrared (FTIR), UV−vis, thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscopy (TEM), and electric conductivity. The diameters of the PPy/LGS nanoparticles decreased from 100 to 20 nm with the increasing LGS. Their electrical conductivities were affected markedly by the dopant amount added. The PPy/LGS have weakly temperature-dependent conductivity over the entire temperature interval from 283 to 423 K. |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie900189j |
in Industrial & engineering chemistry research > Vol. 48 N° 21 (Novembre 2009) . - pp. 9498–9503
[article] Water-dispersed conductive polypyrroles doped with lignosulfonate and the weak temperature dependence of electrical conductivity [texte imprimé] / Chao Yang, Auteur ; Peng Liu, Auteur . - 2010 . - pp. 9498–9503. Chemical engineering Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 48 N° 21 (Novembre 2009) . - pp. 9498–9503
Mots-clés : |
Water-dispersed conductive polypyrroles Chemical oxidative polymerization Lignosulfonate |
Résumé : |
The water-dispersed conductive polypyrroles (PPys) were prepared via the chemical oxidative polymerization with lignosulfonate (LGS), an inexpensive byproduct from pulp processing industries, as a dopant and template for tuning the properties of polypyrrole nanoparticles. The lignosulfonate doped polypyrrole (PPy/LGS) nanoparticles were characterized with Fourier transform infrared (FTIR), UV−vis, thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscopy (TEM), and electric conductivity. The diameters of the PPy/LGS nanoparticles decreased from 100 to 20 nm with the increasing LGS. Their electrical conductivities were affected markedly by the dopant amount added. The PPy/LGS have weakly temperature-dependent conductivity over the entire temperature interval from 283 to 423 K. |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie900189j |
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