Covalently anchored polymer immobilized Co(II) phthalocyanine as efficient catalyst for oxidation of mercaptans using molecular oxygen as oxidant / Jomy K. Joseph in Industrial & engineering chemistry research, Vol. 49 N° 14 (Juillet 2010)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 49 N° 14 (Juillet 2010) . - pp. 6674–6677 Titre : Covalently anchored polymer immobilized Co(II) phthalocyanine as efficient catalyst for oxidation of mercaptans using molecular oxygen as oxidant Type de document : texte imprimé Auteurs : Jomy K. Joseph, Auteur ; Suman L. Jain, Auteur ; Bir Sain, Auteur Année de publication : 2010 Article en page(s) : pp. 6674–6677 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Catalyst Oxidation Résumé : The present paper describes the covalent immobilization of cobalt phthalocyanine “MEROX catalyst” to polystyrene resin via sulfonamide linkage and its catalytic activity for the oxidation of mercaptans to disulfides using molecular oxygen as an oxidant under alkaline conditions. Polymer-supported cobalt phthalocyanine, wherein the catalyst is chemically bounded to the support which prevents the leaching of the catalyst/ligand, can readily be recovered from the reaction mixture and reused for several runs without significant decrease in catalytic activity. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie100351s [article] Covalently anchored polymer immobilized Co(II) phthalocyanine as efficient catalyst for oxidation of mercaptans using molecular oxygen as oxidant [texte imprimé] / Jomy K. Joseph, Auteur ; Suman L. Jain, Auteur ; Bir Sain, Auteur . - 2010 . - pp. 6674–6677. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 14 (Juillet 2010) . - pp. 6674–6677 Mots-clés : Catalyst Oxidation Résumé : The present paper describes the covalent immobilization of cobalt phthalocyanine “MEROX catalyst” to polystyrene resin via sulfonamide linkage and its catalytic activity for the oxidation of mercaptans to disulfides using molecular oxygen as an oxidant under alkaline conditions. Polymer-supported cobalt phthalocyanine, wherein the catalyst is chemically bounded to the support which prevents the leaching of the catalyst/ligand, can readily be recovered from the reaction mixture and reused for several runs without significant decrease in catalytic activity. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie100351s

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Poly(ethylene glycol) embedded potassium tribromide (PEG.KBr3) as a recyclable catalyst for oxidation of alcohols / Sanny Verma in Industrial & engineering chemistry research, Vol. 50 N° 9 (Mai 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 9 (Mai 2011) . - pp. 5862-5865 Titre : Poly(ethylene glycol) embedded potassium tribromide (PEG.KBr3) as a recyclable catalyst for oxidation of alcohols Type de document : texte imprimé Auteurs : Sanny Verma, Auteur ; Suman L. Jain, Auteur ; Bir Sain, Auteur Année de publication : 2011 Article en page(s) : pp. 5862-5865 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Oxidation Catalyst Résumé : An efficient metal free polyethylene glycol wrapped potassium tribromide [PEG.KBr3] has been developed for the first time by using host―guest chemistry. The prepared reagent is found to be an Efficient, stable, cost-effective, and recyclable catalyst for the oxidation of a variety of primary, secondary, 1,2 diols, and α-hydroxy to the corresponding aldehydes, ketones, and 1,2-diketones respectively, in high to excellent yields by using hydrogen peroxide as oxidant. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24128712 [article] Poly(ethylene glycol) embedded potassium tribromide (PEG.KBr3) as a recyclable catalyst for oxidation of alcohols [texte imprimé] / Sanny Verma, Auteur ; Suman L. Jain, Auteur ; Bir Sain, Auteur . - 2011 . - pp. 5862-5865. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 9 (Mai 2011) . - pp. 5862-5865 Mots-clés : Oxidation Catalyst Résumé : An efficient metal free polyethylene glycol wrapped potassium tribromide [PEG.KBr3] has been developed for the first time by using host―guest chemistry. The prepared reagent is found to be an Efficient, stable, cost-effective, and recyclable catalyst for the oxidation of a variety of primary, secondary, 1,2 diols, and α-hydroxy to the corresponding aldehydes, ketones, and 1,2-diketones respectively, in high to excellent yields by using hydrogen peroxide as oxidant. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24128712

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