[article]
| Titre : |
Synthesis and surface properties of glycerol based C8 chain monoethers |
| Type de document : |
texte imprimé |
| Auteurs : |
Sandra Bigot, Auteur ; Herve Bricout, Auteur ; Isabelle Suisse, Auteur |
| Année de publication : |
2011 |
| Article en page(s) : |
pp. 9870-9875 |
| Note générale : |
Chimie industrielle |
| Langues : |
Anglais (eng) |
| Mots-clés : |
Surface properties |
| Résumé : |
The telomerization of butadiene with solketal (1,2-isopropylideneglycerol) in the presence of palladium complexes has been studied under aqueous biphasic conditions. This reaction followed by deprotection in acid medium leads to monooctadienyl ethers of glycerol (linear and branched) with a high selectivity into the linear isomer. The corresponding glyceryl monooctyl ethers are obtained by hydrogenation of the octadienyl ethers. The surface properties ofthese two classes of compounds have been appraised and compared showing the influence of the double bonds on these properties. |
| DEWEY : |
660 |
| ISSN : |
0888-5885 |
| En ligne : |
http://cat.inist.fr/?aModele=afficheN&cpsidt=24483629 |
in Industrial & engineering chemistry research > Vol. 50 N° 17 (Septembre 2011) . - pp. 9870-9875
[article] Synthesis and surface properties of glycerol based C8 chain monoethers [texte imprimé] / Sandra Bigot, Auteur ; Herve Bricout, Auteur ; Isabelle Suisse, Auteur . - 2011 . - pp. 9870-9875. Chimie industrielle Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 50 N° 17 (Septembre 2011) . - pp. 9870-9875
| Mots-clés : |
Surface properties |
| Résumé : |
The telomerization of butadiene with solketal (1,2-isopropylideneglycerol) in the presence of palladium complexes has been studied under aqueous biphasic conditions. This reaction followed by deprotection in acid medium leads to monooctadienyl ethers of glycerol (linear and branched) with a high selectivity into the linear isomer. The corresponding glyceryl monooctyl ethers are obtained by hydrogenation of the octadienyl ethers. The surface properties ofthese two classes of compounds have been appraised and compared showing the influence of the double bonds on these properties. |
| DEWEY : |
660 |
| ISSN : |
0888-5885 |
| En ligne : |
http://cat.inist.fr/?aModele=afficheN&cpsidt=24483629 |
|
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