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Synthesis and surface properties of glycerol based C8 chain monoethers / Sandra Bigot in Industrial & engineering chemistry research, Vol. 50 N° 17 (Septembre 2011) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 50 N° 17 (Septembre 2011) . - pp. 9870-9875 Titre : Synthesis and surface properties of glycerol based C8 chain monoethers Type de document : texte imprimé Auteurs : Sandra Bigot, Auteur ; Herve Bricout, Auteur ; Isabelle Suisse, Auteur Année de publication : 2011 Article en page(s) : pp. 9870-9875 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Surface  properties Résumé : The telomerization of butadiene with solketal (1,2-isopropylideneglycerol) in the presence of palladium complexes has been studied under aqueous biphasic conditions. This reaction followed by deprotection in acid medium leads to monooctadienyl ethers of glycerol (linear and branched) with a high selectivity into the linear isomer. The corresponding glyceryl monooctyl ethers are obtained by hydrogenation of the octadienyl ethers. The surface properties ofthese two classes of compounds have been appraised and compared showing the influence of the double bonds on these properties. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24483629 [article] Synthesis and surface properties of glycerol based C8 chain monoethers [texte imprimé] / Sandra Bigot, Auteur ; Herve Bricout, Auteur ; Isabelle Suisse, Auteur . - 2011 . - pp. 9870-9875. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 17 (Septembre 2011) . - pp. 9870-9875 Mots-clés : Surface  properties Résumé : The telomerization of butadiene with solketal (1,2-isopropylideneglycerol) in the presence of palladium complexes has been studied under aqueous biphasic conditions. This reaction followed by deprotection in acid medium leads to monooctadienyl ethers of glycerol (linear and branched) with a high selectivity into the linear isomer. The corresponding glyceryl monooctyl ethers are obtained by hydrogenation of the octadienyl ethers. The surface properties ofthese two classes of compounds have been appraised and compared showing the influence of the double bonds on these properties. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24483629