Kinetics and mechanism of deamination and decarboxylation of 2-aminopentanedioic acid by quinolinium dichromate (QDC) in aqueous perchloric acid medium / Aftab Aslam Parwaz Khan in Industrial & engineering chemistry research, Vol. 50 N° 17 (Septembre 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 17 (Septembre 2011) . - pp. 9883-9889 Titre : Kinetics and mechanism of deamination and decarboxylation of 2-aminopentanedioic acid by quinolinium dichromate (QDC) in aqueous perchloric acid medium Type de document : texte imprimé Auteurs : Aftab Aslam Parwaz Khan, Auteur ; Ayaz Mohd, Auteur ; Shaista Bano, Auteur Année de publication : 2011 Article en page(s) : pp. 9883-9889 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Acid medium Kinetics Résumé : Kinetic data for the oxidation of 2-aminopentanedioic acid/L-glutamic acid (Glu-e) by quinolinium dichromate (QDC) in perchloric acid medium are reported. The results of the reactions studied spectrophotometrically over a wide range of experimental conditions show that the rate of the reaction is increased by increases in perchloric acid, the ionic strength, and the concentration of Glu-e. The reactions are first order with respect to both QDC and Glu-e. Added products are found to have an insignificant effect on the reaction rate. The activation parameters and thermodynamics have been evaluated and lend further support to the proposed mechanism. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24483631 [article] Kinetics and mechanism of deamination and decarboxylation of 2-aminopentanedioic acid by quinolinium dichromate (QDC) in aqueous perchloric acid medium [texte imprimé] / Aftab Aslam Parwaz Khan, Auteur ; Ayaz Mohd, Auteur ; Shaista Bano, Auteur . - 2011 . - pp. 9883-9889. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 17 (Septembre 2011) . - pp. 9883-9889 Mots-clés : Acid medium Kinetics Résumé : Kinetic data for the oxidation of 2-aminopentanedioic acid/L-glutamic acid (Glu-e) by quinolinium dichromate (QDC) in perchloric acid medium are reported. The results of the reactions studied spectrophotometrically over a wide range of experimental conditions show that the rate of the reaction is increased by increases in perchloric acid, the ionic strength, and the concentration of Glu-e. The reactions are first order with respect to both QDC and Glu-e. Added products are found to have an insignificant effect on the reaction rate. The activation parameters and thermodynamics have been evaluated and lend further support to the proposed mechanism. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24483631

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