Article : texte imprimé

Finding the simplest mechanistic kinetic model describing the homogeneous catalytic hydrogenation of avermectin to ivermectin

Mariano D. Cristaldi, Auteur ; Maria I. Cabrera, Auteur ; Ernesto C. Martinez, Auteur |

Dans Industrial & engineering chemistry research (Vol. 50 N° 8, Avril 2011)

Six mechanistic kinetic models of increasing complexity are analyzed to describe the RhCl(Ph3P)3 catalyzed hydrogenation process to produce ivermectin from avermectins B1a and B1b. Global sensitivity analysis (GSA) usefulness for selecting the s[...]

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