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On the solubility of three disperse anthraquinone dyes in supercritical carbon dioxide / Jose P. Coelho in Industrial & engineering chemistry research, Vol. 50 N° 8 (Avril 2011) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 50 N° 8 (Avril 2011) . - pp. 4618–4624 Titre : On the solubility of three disperse anthraquinone dyes in supercritical carbon dioxide : new experimental data and correlation Type de document : texte imprimé Auteurs : Jose P. Coelho, Auteur ; Andrea F. Mendonça, Auteur ; Antonio F. Palavra, Auteur Année de publication : 2011 Article en page(s) : pp. 4618–4624 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Solubility  measurements  Anthraquinone  Dioxide Résumé : Solubility measurements of quinizarin (1,4-dihydroxyanthraquinone), disperse red 9 (1-(methylamino) anthraquinone), and disperse blue 14 (1,4-bis(methylamino)anthraquinone) in supercritical carbon dioxide (SC CO2) were carried out in a flow type apparatus, at a temperature range from (333.2 to 393.2) K and at pressures from (12.0 to 40.0) MPa. Mole fraction solubility of the three dyes decreases in the order quinizarin (2.9 × 10−6 to 2.9.10−4), red 9 (1.4 × 10−6 to 3.2 × 10−4), and blue 14 (7.8 × 10−8 to 2.2 × 10−5). Four semiempirical density-based models were used to correlate the solubility of the dyes in the SC CO2. From the correlation results, the total heat of reaction, heat of vaporization plus the heat of solvation of the solute, were calculated and compared with the results presented in the literature. The solubilities of the three dyes were correlated also applying the Soave−Redlich−Kwong cubic equation of state (SRK CEoS) with classical mixing rules, and the physical properties required for the modeling were estimated and reported. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie102028x [article] On the solubility of three disperse anthraquinone dyes in supercritical carbon dioxide : new experimental data and correlation [texte imprimé] / Jose P. Coelho, Auteur ; Andrea F. Mendonça, Auteur ; Antonio F. Palavra, Auteur . - 2011 . - pp. 4618–4624. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 8 (Avril 2011) . - pp. 4618–4624 Mots-clés : Solubility  measurements  Anthraquinone  Dioxide Résumé : Solubility measurements of quinizarin (1,4-dihydroxyanthraquinone), disperse red 9 (1-(methylamino) anthraquinone), and disperse blue 14 (1,4-bis(methylamino)anthraquinone) in supercritical carbon dioxide (SC CO2) were carried out in a flow type apparatus, at a temperature range from (333.2 to 393.2) K and at pressures from (12.0 to 40.0) MPa. Mole fraction solubility of the three dyes decreases in the order quinizarin (2.9 × 10−6 to 2.9.10−4), red 9 (1.4 × 10−6 to 3.2 × 10−4), and blue 14 (7.8 × 10−8 to 2.2 × 10−5). Four semiempirical density-based models were used to correlate the solubility of the dyes in the SC CO2. From the correlation results, the total heat of reaction, heat of vaporization plus the heat of solvation of the solute, were calculated and compared with the results presented in the literature. The solubilities of the three dyes were correlated also applying the Soave−Redlich−Kwong cubic equation of state (SRK CEoS) with classical mixing rules, and the physical properties required for the modeling were estimated and reported. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie102028x