Modeling surface tension of concentrated and mixed-solvent electrolyte systems / Peiming Wang in Industrial & engineering chemistry research, Vol. 50 N° 7 (Avril 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 7 (Avril 2011) . - pp. 4086-4098 Titre : Modeling surface tension of concentrated and mixed-solvent electrolyte systems Type de document : texte imprimé Auteurs : Peiming Wang, Auteur ; Andrzej Anderko, Auteur ; Robert D. Young, Auteur Année de publication : 2011 Article en page(s) : pp. 4086-4098 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Electrolyte Mixed solvent Surface tension Modeling Résumé : A comprehensive model has been developed for calculating the surface tension of aqueous, nonaqueous, and mixed-solvent electrolyte systems ranging from dilute solutions to fused salts. The model consists of a correlation for computing the surface tension of solvent mixtures and an expression for the effect of electrolyte concentration. The dependence of surface tension on electrolyte concentration has been derived from the Gibbs equation combined with a modified Langmuir adsorption isotherm for modeling the surface excess of species. The model extends the Langmuir adsorption formalism by introducing the effects of binary interactions between solute species (ions or molecules) on the surface. This extension is especially important for high electrolyte concentrations and in strongly speciated systems. The surface tension of mixed solvents is calculated by utilizing the surface tensions of the constituent pure components together with an effective surface concentration, which is defined for each component and takes into account interactions between solvent molecules. This procedure has been shown to reproduce experimental data for a variety of mixtures. In particular, it accurately predicts the surface tension of temary solvent mixtures using parameters determined from only binary data. The surface tension model has been coupled with a previously developed thermodynamic equilibrium model to provide speciation and activity coefficients, which are necessary for electrolyte systems. This makes it possible to reproduce the effects of complexation or other reactions in solution. In all cases for which experimental data are available and have been tested, the new model has been shown to be accurate in reproducing surface tension over wide ranges of temperature and concentration. The average deviations between the calculated results and experimental data are 0.68% for binary solvent mixtures, 1.89% for ternary solvent mixtures, and 0.71% for salt solutions up to the solid saturation or pure solute limit. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24027656 [article] Modeling surface tension of concentrated and mixed-solvent electrolyte systems [texte imprimé] / Peiming Wang, Auteur ; Andrzej Anderko, Auteur ; Robert D. Young, Auteur . - 2011 . - pp. 4086-4098. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 7 (Avril 2011) . - pp. 4086-4098 Mots-clés : Electrolyte Mixed solvent Surface tension Modeling Résumé : A comprehensive model has been developed for calculating the surface tension of aqueous, nonaqueous, and mixed-solvent electrolyte systems ranging from dilute solutions to fused salts. The model consists of a correlation for computing the surface tension of solvent mixtures and an expression for the effect of electrolyte concentration. The dependence of surface tension on electrolyte concentration has been derived from the Gibbs equation combined with a modified Langmuir adsorption isotherm for modeling the surface excess of species. The model extends the Langmuir adsorption formalism by introducing the effects of binary interactions between solute species (ions or molecules) on the surface. This extension is especially important for high electrolyte concentrations and in strongly speciated systems. The surface tension of mixed solvents is calculated by utilizing the surface tensions of the constituent pure components together with an effective surface concentration, which is defined for each component and takes into account interactions between solvent molecules. This procedure has been shown to reproduce experimental data for a variety of mixtures. In particular, it accurately predicts the surface tension of temary solvent mixtures using parameters determined from only binary data. The surface tension model has been coupled with a previously developed thermodynamic equilibrium model to provide speciation and activity coefficients, which are necessary for electrolyte systems. This makes it possible to reproduce the effects of complexation or other reactions in solution. In all cases for which experimental data are available and have been tested, the new model has been shown to be accurate in reproducing surface tension over wide ranges of temperature and concentration. The average deviations between the calculated results and experimental data are 0.68% for binary solvent mixtures, 1.89% for ternary solvent mixtures, and 0.71% for salt solutions up to the solid saturation or pure solute limit. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24027656

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