Hydrothermal synthesis of CuO nanoparticles / M. Outokesh in Industrial & engineering chemistry research, Vol. 50 N° 6 (Mars 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 6 (Mars 2011) . - pp. 3540–3554 Titre : Hydrothermal synthesis of CuO nanoparticles : study on effects of operational conditions on yield, purity, and size of the nanoparticles Type de document : texte imprimé Auteurs : M. Outokesh, Auteur ; M. Hosseinpour, Auteur ; S. J. Ahmadi, Auteur Année de publication : 2011 Article en page(s) : pp. 3540–3554 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Hydrothermal Nanoparticles Résumé : Hydrothermal synthesis of CuO nanoparticles under near-critical and supercritical conditions was investigated from two different standpoints in the current study. The first standpoint was optimization of “yield”, “purity”, and “size of the nanoparticles” that were optimized at T = 500 °C, time = 2 h, [Cu(NO3)2] = 0.1 mol dm−3, and pH 3. This was achieved by undertaking an orthogonal experiment design methodology and performing different instrumental analyses, such as X-ray diffractometry, inductively coupled plasma spectrometry, and transmission electron microscopy, along with treatment of the data by analysis of variance (ANOVA). The second goal of the study was elucidation of the mechanisms of effects of operational conditions (e.g., temperature) on the above-mentioned target parameters, through application of the appropriate mechanisms of formation of nanoparticles. Nanoparticles are suggested to form initially in the liquid phase as Cu(OH)2, which are later transformed to Cu2(OH)3NO3, through which CuO product is obtained. Decomposition of nitric acid also plays role in this mechanism. Fabricated nanoparticles are effective catalysts for the synthesis of benzoheterocycle compounds in the pharmaceutical industries. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie1017089 [article] Hydrothermal synthesis of CuO nanoparticles : study on effects of operational conditions on yield, purity, and size of the nanoparticles [texte imprimé] / M. Outokesh, Auteur ; M. Hosseinpour, Auteur ; S. J. Ahmadi, Auteur . - 2011 . - pp. 3540–3554. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 6 (Mars 2011) . - pp. 3540–3554 Mots-clés : Hydrothermal Nanoparticles Résumé : Hydrothermal synthesis of CuO nanoparticles under near-critical and supercritical conditions was investigated from two different standpoints in the current study. The first standpoint was optimization of “yield”, “purity”, and “size of the nanoparticles” that were optimized at T = 500 °C, time = 2 h, [Cu(NO3)2] = 0.1 mol dm−3, and pH 3. This was achieved by undertaking an orthogonal experiment design methodology and performing different instrumental analyses, such as X-ray diffractometry, inductively coupled plasma spectrometry, and transmission electron microscopy, along with treatment of the data by analysis of variance (ANOVA). The second goal of the study was elucidation of the mechanisms of effects of operational conditions (e.g., temperature) on the above-mentioned target parameters, through application of the appropriate mechanisms of formation of nanoparticles. Nanoparticles are suggested to form initially in the liquid phase as Cu(OH)2, which are later transformed to Cu2(OH)3NO3, through which CuO product is obtained. Decomposition of nitric acid also plays role in this mechanism. Fabricated nanoparticles are effective catalysts for the synthesis of benzoheterocycle compounds in the pharmaceutical industries. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie1017089

Exemplaires

Code-barres	Cote	Support	Localisation	Section	Disponibilité
aucun exemplaire