[article]
Titre : |
Application of sulfonated carbon - based catalyst for reactive extraction of 1,3-propanediol from model fermentation mixture |
Type de document : |
texte imprimé |
Auteurs : |
Panatpong Boonoun, Auteur ; Navadol Laosiripojana, Auteur ; Chirakarn Muangnapoh, Auteur |
Année de publication : |
2011 |
Article en page(s) : |
pp. 12352-12357 |
Note générale : |
Chimie industrielle |
Langues : |
Anglais (eng) |
Mots-clés : |
Fermentation Modeling Catalyst |
Résumé : |
This study deals with the possibility of the application of a low-cost sulfonated carbon-based catalyst for reactive extraction to separate 1,3-propanediol (1,3-PDO) from a model solution of 1,3-PDO biologically derived from glycerol. The catalyst was synthesized by incomplete carbonization of naphthalene in sulfuric acid, and was demonstrated to be active for the acetalization of 1,3-PDO with acetaldehyde in aqueous solution. The performance of the reactive extraction process by using a sulfonated carbon-based catalyst was proven to be excellent based on the percent recovery rate of 1,3-PDO. These results along with those on the catalyst reactivity demonstrate that the carbon-based catalyst can be used to replace expensive commercial catalysts currently used such as Dowex 50-WX4-200 and Amberlite IR120. |
DEWEY : |
660 |
ISSN : |
0888-5885 |
En ligne : |
http://cat.inist.fr/?aModele=afficheN&cpsidt=23691986 |
in Industrial & engineering chemistry research > Vol. 49 N° 24 (Décembre 2010) . - pp. 12352-12357
[article] Application of sulfonated carbon - based catalyst for reactive extraction of 1,3-propanediol from model fermentation mixture [texte imprimé] / Panatpong Boonoun, Auteur ; Navadol Laosiripojana, Auteur ; Chirakarn Muangnapoh, Auteur . - 2011 . - pp. 12352-12357. Chimie industrielle Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 49 N° 24 (Décembre 2010) . - pp. 12352-12357
Mots-clés : |
Fermentation Modeling Catalyst |
Résumé : |
This study deals with the possibility of the application of a low-cost sulfonated carbon-based catalyst for reactive extraction to separate 1,3-propanediol (1,3-PDO) from a model solution of 1,3-PDO biologically derived from glycerol. The catalyst was synthesized by incomplete carbonization of naphthalene in sulfuric acid, and was demonstrated to be active for the acetalization of 1,3-PDO with acetaldehyde in aqueous solution. The performance of the reactive extraction process by using a sulfonated carbon-based catalyst was proven to be excellent based on the percent recovery rate of 1,3-PDO. These results along with those on the catalyst reactivity demonstrate that the carbon-based catalyst can be used to replace expensive commercial catalysts currently used such as Dowex 50-WX4-200 and Amberlite IR120. |
DEWEY : |
660 |
ISSN : |
0888-5885 |
En ligne : |
http://cat.inist.fr/?aModele=afficheN&cpsidt=23691986 |
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