Stable citrate - coated iron oxide superparamagnetic nanoclusters at high salinity / Csaba Kotsmar in Industrial & engineering chemistry research, Vol. 49 N° 24 (Décembre 2010)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 49 N° 24 (Décembre 2010) . - pp. 12435–12443 Titre : Stable citrate - coated iron oxide superparamagnetic nanoclusters at high salinity Type de document : texte imprimé Auteurs : Csaba Kotsmar, Auteur ; Ki Youl Yoon, Auteur ; Haiyang Yu, Auteur Année de publication : 2011 Article en page(s) : pp. 12435–12443 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Superparamagnetic nanoclusters Résumé : Superparamagnetic nanoclusters may be used in imaging in biomedicine and in mapping of petroleum reservoirs, by generating either ultrasonic or acoustic signals with oscillating magnetic motion. For a given magnetization per weight of iron oxide, nanoclusters with diameters from 20 to 100 nm experience a much larger magnetic force than that of the primary sub-10-nm primary particles. Aqueous dispersions of 0.1 wt % superparamagnetic iron oxide nanoclusters were stabilized with citric acid on the particle surface, with a high loading of 90% iron oxide. The dispersions were stable for months even with high salt concentrations up to 4 wt % at a pH of 6 and 8 based on the hydrodynamic diameter from dynamic light scattering. The citrate ligands provide electrostatic repulsion, as characterized by the ζ potential. The small size of the clusters, superparamagnetic properties, and high salt tolerance are highly beneficial in various applications including the mapping of petroleum reservoirs with magnetomotive techniques. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie1010965 [article] Stable citrate - coated iron oxide superparamagnetic nanoclusters at high salinity [texte imprimé] / Csaba Kotsmar, Auteur ; Ki Youl Yoon, Auteur ; Haiyang Yu, Auteur . - 2011 . - pp. 12435–12443. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 24 (Décembre 2010) . - pp. 12435–12443 Mots-clés : Superparamagnetic nanoclusters Résumé : Superparamagnetic nanoclusters may be used in imaging in biomedicine and in mapping of petroleum reservoirs, by generating either ultrasonic or acoustic signals with oscillating magnetic motion. For a given magnetization per weight of iron oxide, nanoclusters with diameters from 20 to 100 nm experience a much larger magnetic force than that of the primary sub-10-nm primary particles. Aqueous dispersions of 0.1 wt % superparamagnetic iron oxide nanoclusters were stabilized with citric acid on the particle surface, with a high loading of 90% iron oxide. The dispersions were stable for months even with high salt concentrations up to 4 wt % at a pH of 6 and 8 based on the hydrodynamic diameter from dynamic light scattering. The citrate ligands provide electrostatic repulsion, as characterized by the ζ potential. The small size of the clusters, superparamagnetic properties, and high salt tolerance are highly beneficial in various applications including the mapping of petroleum reservoirs with magnetomotive techniques. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie1010965

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