| Titre : | Measurement of autogenous pressure and dissociated species during the thermolysis of mesitylene for the synthesis of monodispersed, pure, paramagnetic carbon particles (2009) |
| Auteurs : | Pol, Vilas G., Auteur ; P. Thiyagarajan, Auteur |
| Type de document : | Article : texte imprimé |
| Dans : | Industrial & engineering chemistry research (Vol. 48 N°3, Février 2009) |
| Article en page(s) : | p. 1484–1489 |
| Note générale : | Chemical engineering |
| Langues : | Anglais |
| Tags : | spherical carbon particles Autogenous pressure Mesitylene |
| Résumé : |
Two reaction parameters are important for the synthesis of entirely monodispersed, pure, paramagnetic spherical carbon particles. The experimental setup is developed to measure in situ autogenous pressure as a function of temperature during the thermolysis of mesitylene in a closed reactor. In situ mass spectrometry analyzed the dissociated species during the heating cycle of mesitylene as a function of temperature. The morphology, structure, composition, and magnetic properties of the as-prepared spherical carbon particles are characterized by using SEM, XRD, Raman spectroscopy, EDX, CHNS analysis, and EPR. |
| En ligne : | http://pubs.acs.org/doi/abs/10.1021/ie8014928 |
