Esterification of acetic acid and isobutanol in a pervaporation membrane reactor using different membranes / Sevinc Korkmaz in Industrial & engineering chemistry research, Vol. 50 N° 20 (Octobre 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 20 (Octobre 2011) . - pp. 11657-11666 Titre : Esterification of acetic acid and isobutanol in a pervaporation membrane reactor using different membranes Type de document : texte imprimé Auteurs : Sevinc Korkmaz, Auteur ; Yavuz Salt, Auteur ; Salih Dincer, Auteur Année de publication : 2011 Article en page(s) : pp. 11657-11666 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Membrane reactor separation Pervaporation Esterification Résumé : In this study the ester-permeable polydimethylsiloxane (PDMS) and the water-permeable poly(vinyl alcohol) membranes prepared in our laboratory and the commercial Nafion 117, PERVAP 1201, and PERVAP 2216 membranes were used in the esterification of acetic acid with isobutanol catalyzed by Dowex 50W-X8 in a pervaporation membrane reactor process in order to shift the equilibrium by removal of relevant product from the reaction mixture. The effects of membrane type, the ratio of membrane area to reaction volume, and temperature were investigated. PERVAP 1201 membranes provided a higher water flux and higher selectivity than other hydrophilic membranes, but the highest fluxes were obtained using PDMS membrane, which selectively permeated isobutyl acetate compared to the other components. Increase in temperature and ratio of membrane area to reaction volume increased the conversion. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24612391 [article] Esterification of acetic acid and isobutanol in a pervaporation membrane reactor using different membranes [texte imprimé] / Sevinc Korkmaz, Auteur ; Yavuz Salt, Auteur ; Salih Dincer, Auteur . - 2011 . - pp. 11657-11666. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 20 (Octobre 2011) . - pp. 11657-11666 Mots-clés : Membrane reactor separation Pervaporation Esterification Résumé : In this study the ester-permeable polydimethylsiloxane (PDMS) and the water-permeable poly(vinyl alcohol) membranes prepared in our laboratory and the commercial Nafion 117, PERVAP 1201, and PERVAP 2216 membranes were used in the esterification of acetic acid with isobutanol catalyzed by Dowex 50W-X8 in a pervaporation membrane reactor process in order to shift the equilibrium by removal of relevant product from the reaction mixture. The effects of membrane type, the ratio of membrane area to reaction volume, and temperature were investigated. PERVAP 1201 membranes provided a higher water flux and higher selectivity than other hydrophilic membranes, but the highest fluxes were obtained using PDMS membrane, which selectively permeated isobutyl acetate compared to the other components. Increase in temperature and ratio of membrane area to reaction volume increased the conversion. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24612391

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