| Titre : | Lumped kinetics of self-heating runaway reactions : a statistical treatment (2008) |
| Auteurs : | Enio Kumpinsky, Éditeur scientifique |
| Type de document : | Article : texte imprimé |
| Dans : | Industrial & engineering chemistry research (Vol. 47 N°20, Octobre 2008) |
| Article en page(s) : | P. 7570-7579 |
| Note générale : | Chemical engineering |
| Langues : | Anglais |
| Tags : | Lumped kinetics Self-heating Chemical industry Statistical Treatment |
| Résumé : | The evaluation of laboratory-scale runaway reactions is of fundamental importance to safety studies that seek mitigation of hazards in the chemical industry. Such studies depend on reaction kinetics, which require good experimentation practices and effective interpretation of the results. Statistics offer many tools for the analysis of experimental data. Parameters can be estimated and re-evaluated to reduce collinearity between the factors. In addition, experimental variability and deficient model performance at temperatures in the neighborhood of venting conditions can be properly managed to provide conservative reaction rates without exaggerating the hazard. |
| En ligne : | http://pubs.acs.org/doi/abs/10.1021/ie0714201 |
