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Determination of chlorobenzene solubilities in subcritical water in a fused silica capillary reactor from 173 to 267 °C / Zhiyan Pan in Industrial & engineering chemistry research, Vol. 50 N° 20 (Octobre 2011) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 50 N° 20 (Octobre 2011) . - pp. 11724-11727 Titre : Determination of chlorobenzene solubilities in subcritical water in a fused silica capillary reactor from 173 to 267 °C Type de document : texte imprimé Auteurs : Zhiyan Pan, Auteur ; Zhong Dong, Auteur Année de publication : 2011 Article en page(s) : pp. 11724-11727 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Reactor  Solubility Résumé : The solubility of chlorobenzene was measured in subcritical water using a fused silica capillary reactor (FSCR) combined with a microscope recorder system to capture the images and identify the temperature of total dissolution. The solubility of chlorobenzene was found to vary between 43.5 mg g-1 in water at 173.3 °C and 71.4 mg g-1 in water at 266.9 °C, increasing linearly with temperature. A new approximation model was developed to predict the solubility of chlorobenzene in subcritical water at elevated temperatures. This visualization in the FSCR method does not require sampling and subsequent analysis, and it has a great potential for the solubility determinations of other organic or inorganic materials. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24612399 [article] Determination of chlorobenzene solubilities in subcritical water in a fused silica capillary reactor from 173 to 267 °C [texte imprimé] / Zhiyan Pan, Auteur ; Zhong Dong, Auteur . - 2011 . - pp. 11724-11727. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 20 (Octobre 2011) . - pp. 11724-11727 Mots-clés : Reactor  Solubility Résumé : The solubility of chlorobenzene was measured in subcritical water using a fused silica capillary reactor (FSCR) combined with a microscope recorder system to capture the images and identify the temperature of total dissolution. The solubility of chlorobenzene was found to vary between 43.5 mg g-1 in water at 173.3 °C and 71.4 mg g-1 in water at 266.9 °C, increasing linearly with temperature. A new approximation model was developed to predict the solubility of chlorobenzene in subcritical water at elevated temperatures. This visualization in the FSCR method does not require sampling and subsequent analysis, and it has a great potential for the solubility determinations of other organic or inorganic materials. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24612399